Production of renewable C4-C6 monoalcohols from waste biomass-derived carbohydrate via aqueous-phase hydrodeoxygenation over Pt-ReOx/Zr-P
DC Field | Value | Language |
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dc.contributor.author | Lee, Jechan | - |
dc.contributor.author | Ro, Insoo | - |
dc.contributor.author | Kim, Hyung Ju | - |
dc.contributor.author | Kim, Yong The | - |
dc.contributor.author | Kwon, Eilhann E. | - |
dc.contributor.author | Huber, George W. | - |
dc.date.accessioned | 2023-09-18T06:58:39Z | - |
dc.date.available | 2023-09-18T06:58:39Z | - |
dc.date.created | 2023-07-07 | - |
dc.date.issued | 2018-04 | - |
dc.identifier.issn | 0957-5820 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/190826 | - |
dc.description.abstract | A bifunctional catalyst, Pt-ReOx, supported on zirconium phosphate (Pt-ReOx/Zr-P), was prepared and tested for aqueous-phase hydrodeoxygenation (APHDO) of waste biomass-derived carbohydrate (e.g., sorbitol) to produce C4-C6 monoalcohols such as butanol, pentanol, and hexanol in a high-pressure continuous flow reactor. For steady-state operation, the reaction parameters were optimized to achieve the highest yield of C4-C6 monoalcohols from APHDO of sorbitol. Approximately 30% yield of C4-C6 monoalcohols was reached at optimal reaction conditions (temperature: 453 K, pressure: 6.21 MPa, weight hourly space velocity (WHSV): 0.16 h(-1)) for APHDO of sorbitol over the Pt-ReOx/Zr-P catalyst. The effect of catalyst support for monoalcohol production was also evaluated by comparison between the Pt-ReOx/Zr-P and carbon supported Pt-ReOx (Pt-ReOx/C) catalysts. The Zr-P supported catalyst exhibited a four times higher yield of C4-C6 monoalcohols than the carbon supported catalyst, suggesting that acid sites atomically separated from metal sites play a crucial role in producing monoalcohols via C-O bond cleavage of chemical intermediates produced during APHDO of sorbitol. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | INST CHEMICAL ENGINEERS | - |
dc.title | Production of renewable C4-C6 monoalcohols from waste biomass-derived carbohydrate via aqueous-phase hydrodeoxygenation over Pt-ReOx/Zr-P | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kwon, Eilhann E. | - |
dc.identifier.doi | 10.1016/j.psep.2017.05.015 | - |
dc.identifier.scopusid | 2-s2.0-85020637144 | - |
dc.identifier.wosid | 000431939800002 | - |
dc.identifier.bibliographicCitation | Process Safety and Environmental Protection, v.115, pp.2 - 7 | - |
dc.relation.isPartOf | Process Safety and Environmental Protection | - |
dc.citation.title | Process Safety and Environmental Protection | - |
dc.citation.volume | 115 | - |
dc.citation.startPage | 2 | - |
dc.citation.endPage | 7 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | PLATINUM-RHENIUM CATALYSTS | - |
dc.subject.keywordPlus | CARBON-SUPPORTED PLATINUM | - |
dc.subject.keywordPlus | CLOSTRIDIUM-ACETOBUTYLICUM | - |
dc.subject.keywordPlus | BIOBUTANOL PRODUCTION | - |
dc.subject.keywordPlus | SYNTHESIS GAS | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | PHOSPHATE | - |
dc.subject.keywordPlus | GLYCEROL | - |
dc.subject.keywordPlus | SORBITOL | - |
dc.subject.keywordPlus | FUEL | - |
dc.subject.keywordAuthor | C4-C6 monoalcohols | - |
dc.subject.keywordAuthor | Hydrodeoxygenation | - |
dc.subject.keywordAuthor | Pt-ReOx/Zr-P | - |
dc.subject.keywordAuthor | Sorbitol | - |
dc.subject.keywordAuthor | Biofuels | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0957582017301787?via%3Dihub | - |
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