High-Performance Solid Oxide Fuel Cell with an Electrochemically Surface-Tailored Oxygen Electrode
DC Field | Value | Language |
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dc.contributor.author | Park, Beom-Kyeong | - |
dc.contributor.author | Lee, Seung-Bok | - |
dc.contributor.author | Lim, Tak-Hyoung | - |
dc.contributor.author | Song, Rak-Hyun | - |
dc.contributor.author | Lee, Jong-Won | - |
dc.date.accessioned | 2023-09-18T07:15:55Z | - |
dc.date.available | 2023-09-18T07:15:55Z | - |
dc.date.created | 2023-07-07 | - |
dc.date.issued | 2018-08 | - |
dc.identifier.issn | 1864-5631 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/190951 | - |
dc.description.abstract | State-of-the-art cathodes for solid oxide fuel cells (SOFCs), such as (La,Sr)MnO3-(Y2O3)(0.08)(ZrO2)(0.92) (LSM-YSZ), suffer from sluggish oxygen reduction reaction (ORR) kinetics at reduced temperatures, leading to a significant decline in their performance. Herein, we report a tailored SOFC cathode with high ORR activity at intermediate temperatures using a simple but effective approach based on electrochemical surface modification. The proposed process involves chemically assisted electrodeposition (CAED) of a metal hydroxide (LaCo(OH)(x)) on LSM-YSZ surfaces followed by insitu thermal conversion of LaCo(OH)(x) to perovskite-type LaCoO3 (LCO) nanoparticles during the SOFC startup. This method facilitates easy loading of the LCO nanoparticles with a precisely controlled morphology without the need for repeated deposition/annealing processes. An anode-supported SOFC with the LCO-tailored LSM-YSZ electrode exhibits a remarkably increased power density, approximately 180% at 700 degrees C, compared with an SOFC with the pristine electrode as well as excellent long-term stability, which are attributed to the beneficial role of the CAED-derived LCO nanoparticles in enlarging the active areas for ORR and promoting oxygen adsorption/diffusion. This work demonstrates that controlled surface tailoring of the cathode by CAED could be an effective approach for improving the performance of SOFCs at reduced temperatures. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | High-Performance Solid Oxide Fuel Cell with an Electrochemically Surface-Tailored Oxygen Electrode | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lee, Jong-Won | - |
dc.identifier.doi | 10.1002/cssc.201800962 | - |
dc.identifier.scopusid | 2-s2.0-85050687237 | - |
dc.identifier.wosid | 000441237800019 | - |
dc.identifier.bibliographicCitation | CHEMSUSCHEM, v.11, no.15, pp.2620 - 2627 | - |
dc.relation.isPartOf | CHEMSUSCHEM | - |
dc.citation.title | CHEMSUSCHEM | - |
dc.citation.volume | 11 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 2620 | - |
dc.citation.endPage | 2627 | - |
dc.type.rims | ART | - |
dc.type.docType | 정기학술지(Article(Perspective Article포함)) | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Green & Sustainable Science & Technology | - |
dc.subject.keywordPlus | CATHODE | - |
dc.subject.keywordPlus | SOFC | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.subject.keywordPlus | COMPOSITE | - |
dc.subject.keywordPlus | PEROVSKITE | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | IMPEDANCE | - |
dc.subject.keywordPlus | FILM | - |
dc.subject.keywordPlus | (LA,SR)MNO3 | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordAuthor | electrodeposition | - |
dc.subject.keywordAuthor | energy conversion | - |
dc.subject.keywordAuthor | perovskite phases | - |
dc.subject.keywordAuthor | solid oxide fuel cell | - |
dc.subject.keywordAuthor | surface tailoring | - |
dc.identifier.url | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.201800962 | - |
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