Structure-Performance Relationship of Aromatic Polymer Binder for Silicon Anode in Lithium-Ion Batteries
DC Field | Value | Language |
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dc.contributor.author | Kim, Junho | - |
dc.contributor.author | Kim, Gyuri | - |
dc.contributor.author | Park, You Kyung | - |
dc.contributor.author | Lim, Gayoung | - |
dc.contributor.author | Kim, Seung Tae | - |
dc.contributor.author | Jung, In Hwan | - |
dc.contributor.author | Kim, Hansu | - |
dc.date.accessioned | 2023-11-24T04:59:23Z | - |
dc.date.available | 2023-11-24T04:59:23Z | - |
dc.date.created | 2023-07-25 | - |
dc.date.issued | 2023-10 | - |
dc.identifier.issn | 1616-301X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/193000 | - |
dc.description.abstract | Polymer binders are essential for Silicon (Si) anode-based lithium-ion batteries (LIBs). However, the synthetic guidance for aromatic polymer binder is relatively less explored compared to aliphatic polymer binders. In this study, polyimide-based aromatic polymer binders are developed that have strong binding affinity with Si particles, a conductive agent and copper (Cu) current collector, and they show an improved initial discharge capacity of 2663 mAh g(-1), which is 29% higher than that of Kapton-based one (2071 mAh g(-1)). The copolymerization between "hard" and "soft" segments is crucial to achieve reversible volume expansion/contraction during the repeated charging/discharging process, resulting in the best cycle performance. The new binder ensures both excellent volume retention after full-delithiation and allowed volume expansion at least to some extent upon full-lithiation. This Study finds a power-law relationship between the capacity of Si anode and the mechanical properties of the binder, i.e., the tensile stress (& sigma;) and strain (e). The initial discharge capacity is proportional to & sigma;(n) & BULL; e (n = 2.3-2.7). Such an understanding of the relationships between polymer structure, mechanical properties of the polymer and binder performance clearly revealed the importance of the soft-hard polymer structure for aromatic binders used in Si-based high-capacity lithium storage materials. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Structure-Performance Relationship of Aromatic Polymer Binder for Silicon Anode in Lithium-Ion Batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Jung, In Hwan | - |
dc.contributor.affiliatedAuthor | Kim, Hansu | - |
dc.identifier.doi | 10.1002/adfm.202303810 | - |
dc.identifier.scopusid | 2-s2.0-85164165852 | - |
dc.identifier.wosid | 001022782300001 | - |
dc.identifier.bibliographicCitation | ADVANCED FUNCTIONAL MATERIALS, v.33, no.44, pp.1 - 8 | - |
dc.relation.isPartOf | ADVANCED FUNCTIONAL MATERIALS | - |
dc.citation.title | ADVANCED FUNCTIONAL MATERIALS | - |
dc.citation.volume | 33 | - |
dc.citation.number | 44 | - |
dc.citation.startPage | 1 | - |
dc.citation.endPage | 8 | - |
dc.type.rims | ART | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | ELECTROCHEMICAL PROPERTIES | - |
dc.subject.keywordPlus | PHASE-TRANSFORMATIONS | - |
dc.subject.keywordAuthor | Li-ion batteries | - |
dc.subject.keywordAuthor | polymer binders | - |
dc.subject.keywordAuthor | silicon anodes | - |
dc.subject.keywordAuthor | soft-hard copolymers | - |
dc.subject.keywordAuthor | tensile stress-strain relationship | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/adfm.202303810 | - |
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