Influences of alumina type and sulfate content on hydration and physicochemical changes in Portland–limestone cement

Abstract

This study explored the influence of alumina type and gypsum content on the hydration, mechanical properties, and chemical changes of Portland–limestone cement (PLC) using isothermal calorimetry, inductively coupled plasma-optical emission spectroscopy (ICP-OES), ionic chromatography (IC), compressive strength testing, X-ray diffraction (XRD), 27Al magic angle spinning nuclear magnetic resonance (27Al MAS NMR) spectroscopy, and mercury intrusion porosimetry (MIP) testing. The addition of alumina shortened the induction period, accelerated the acceleration period, and increased the mechanical strength of the PLC pastes with 3 and 7 wt% gypsum. The acceleration effect and strength enhancement were not distinct in the PLC pastes with less gypsum (0.1 wt%). The addition of γ-alumina led to the greatest accelerating effect and strength improvement in the PLC pastes with 3 and 7 wt% gypsum, and the compressive strength achieved was comparable to those of pure Ordinary Portland cement (OPC) pastes without limestone. The addition of γ-alumina induced the rapid dissolution of gypsum and consumption of sulfate ions. The chemical change affected by the addition of alumina varied greatly depending on the gypsum content, and trends in AFt and AFm formation in the PLC pastes with different gypsum contents were confirmed. Finally, pore size refinement was observed through the addition of alumina to PLC pastes with 3 and 7 wt% gypsum.