Insight into electro chemical and dielectric properties of flower shaped samarium embedded Y2O3@SeO2 nanocomposites for H2O2 sensor applications

Abstract

The rapid advancement in the sensor technology is critically influencing structure and morphology of the materials used. The researchers are taking keen interest in developing novel materials as sensors and actuators. In this work, Samarium doped Y2O3 @SeO2 (Smx:Y2O3 @SeO2, x = 1%, 8% and 12%) nanocomposites (NC) have been synthesized using microwave assisted method. The effect of Sm3+ substitution over Y2O3 @SeO2 NC have been explored for morphological, structural, optical, sensor and dielectric properties. Crystal structure have been examined by X-ray diffraction (XRD) pattern and showed mixed phase of hexagonal/cubic structure. Morphology of the grains significantly affected by Sm3+ doping, resulted into flower/flake like microstructure. Redshift in optical absorption peak attributed to the enhancement of defect density with Sm3+ doping. The measurement of in depth morphology of the NC investigated using transmission electron microscopy (TEM), showed flower/flake shaped grains with size ∼ 16 nm. Frequency dependence real (ɛ') and imaginary parts (ɛ'') of dielectric constants at various temperatures ranging from 50 °C to 250 °C showed increase in (ɛ') as Sm3+ doping increases on Y2O3 @SeO2 NC. The Sm12%:Y2O3 @SeO2 showed greater sensitivity towards hydrogen peroxide (H2O2) when exposed to volatile gases as compared with Y2O3 @SeO2 NC. An exceptional limit of detection (LOD) of ∼0.68 μM has been realized. The non-enzymatic sensor was capable of detecting H2O2 with a wide linear range of 2–350 μM, linear regression of R2 = 0.991 with a high sensitivity of 26 μA mM−1. The present investigation can be used to develop sensors, optoelectronic devices and actuators.