Exploring the potential of pulverized oyster shell as a limestone substitute in limestone calcined clay cement (LC3) and its implications for performance

Abstract

With the advent of rapid climate change and global warming, the cement industry has been actively striving to minimize its carbon footprint. An effective approach for reducing carbon emissions is to utilize supplementary cementitious materials (SCMs). Limestone calcined clay cement (LC3) has garnered significant attention because of its ability to reduce clinker use by approximately 45 wt%, compared to ordinary Portland cement. However, the raw materials involved in LC3 production, which are obtained through mining and heating of raw clay, also counts toward the carbon footprint. Therefore, the present study aims to explore the feasibility of using oyster shells as a replacement for limestone in LC3 systems. Various amorphousness of calcined clay were tested to investigate the hydration reaction and strength of the oyster shell calcined clay cement (OC3). Data collected using techniques such as X-ray diffraction, thermogravimetry, scanning electron microscopy, isothermal calorimetry, compressive strength testing, and 29Si nuclear magnetic resonance spectroscopy were analyzed to elucidate the hydration reaction mechanisms of OC3, considering the type of calcite (oyster shell or limestone) and the extent of the transformation of kaolinite clay to metakaolin. The findings of this study demonstrate that oyster shells can effectively replace limestone as a raw material for LC3. Furthermore, the irregular morphology of the shell particles enhanced the hydration reaction and development of the cement's microstructure.