Synthesis and Characterization of a New Phenanthrenequinoxaline-Based Polymer for Organic Solar Cells
DC Field | Value | Language |
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dc.contributor.author | Jo, Eunsol | - |
dc.contributor.author | Park, Jong Baek | - |
dc.contributor.author | Lee, Woo-Hyung | - |
dc.contributor.author | Kim, Ji-Hoon | - |
dc.contributor.author | Jung, In Hwan | - |
dc.contributor.author | Hwang, Do-Hoon | - |
dc.contributor.author | Kang, In-Nam | - |
dc.date.accessioned | 2021-08-02T16:27:44Z | - |
dc.date.available | 2021-08-02T16:27:44Z | - |
dc.date.created | 2021-05-14 | - |
dc.date.issued | 2016-09 | - |
dc.identifier.issn | 0887-624X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/22185 | - |
dc.description.abstract | Two donor-acceptor (D-A) conjugated polymers, PQx and PphQx, composed of alkylthienyl-substituted benzo[1,2-b:4,5-b'] dithiophene (BDTT) as the electron donor and the new electron acceptors quinoxaline (Qx) or phenanthrenequinoxaline (phQx), were synthesized with Stille cross-coupling reactions. The number-averaged molecular weights (M-n) of PQx and PphQx were found to be 25.1 and 23.2 kDa, respectively, with a dispersity of 2.6. The band-gap energies of PQx and PphQx are 1.82 and 1.75 eV, respectively. These results indicate that, because phQx units have highly planar structures, their inclusion in D-A polymers will be a very effective method for increasing the polymers' effective conjugation lengths. The hole mobilities of PQx and PphQx were determined to be 5.0 x 10(-5) and 2.2 x 10(-4) cm(2) V-1 s(-1), respectively. A polymer solar cell device prepared with PphQx as the active layer was found to exhibit a power conversion efficiency (PCE) of 5.03%; thus, the introduction of phQx units enhanced both the short circuit current density and PCE of the device. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY | - |
dc.title | Synthesis and Characterization of a New Phenanthrenequinoxaline-Based Polymer for Organic Solar Cells | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Jung, In Hwan | - |
dc.identifier.doi | 10.1002/pola.28166 | - |
dc.identifier.scopusid | 2-s2.0-84971290078 | - |
dc.identifier.wosid | 000383675800018 | - |
dc.identifier.bibliographicCitation | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.54, no.17, pp.2804 - 2810 | - |
dc.relation.isPartOf | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.citation.title | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.citation.volume | 54 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 2804 | - |
dc.citation.endPage | 2810 | - |
dc.type.rims | ART | - |
dc.type.docType | 정기학술지(Article(Perspective Article포함)) | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | PHOTOVOLTAIC PROPERTIES | - |
dc.subject.keywordPlus | AGGREGATION | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | OLIGOMERS | - |
dc.subject.keywordAuthor | charge transport | - |
dc.subject.keywordAuthor | conjugated polymers | - |
dc.subject.keywordAuthor | functionalization of polymers | - |
dc.subject.keywordAuthor | heteroatom-containing polymers | - |
dc.subject.keywordAuthor | organic solar cell | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/10.1002/pola.28166 | - |
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