Reconfigurable chiroptical nanocomposites with chirality transfer from the macro- to the nanoscale
DC Field | Value | Language |
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dc.contributor.author | Kim, Yoonseob | - |
dc.contributor.author | Yeom, Bongjun | - |
dc.contributor.author | Arteaga, Oriol | - |
dc.contributor.author | Yoo, Seung Jo | - |
dc.contributor.author | Lee, Sang-Gil | - |
dc.contributor.author | Kim, Jin-Gyu | - |
dc.contributor.author | Kotov, Nicholas A. | - |
dc.date.accessioned | 2021-08-02T16:54:28Z | - |
dc.date.available | 2021-08-02T16:54:28Z | - |
dc.date.created | 2021-05-14 | - |
dc.date.issued | 2016-04 | - |
dc.identifier.issn | 1476-1122 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/23172 | - |
dc.description.abstract | Nanostructures with chiral geometries exhibit strong polarization rotation. However, achieving reversible modulation of chirality and polarization rotation in device-friendly solid-state films is difficult for rigid materials. Here, we describe nanocomposites, made by conformally coating twisted elastic substrates with films assembled layer-by-layer from plasmonic nanocolloids, whose nanoscale geometry and rotatory optical activity can be reversibly reconfigured and cyclically modulated by macroscale stretching, with up to tenfold concomitant increases in ellipticity. We show that the chiroptical activity at 660nm of gold nanoparticle composites is associated with circular extinction from linear effects. The polarization rotation at 550nm originates from the chirality of nanoparticle chains with an S-like shape that exhibit a non-planar buckled geometry, with the handedness of the substrate's macroscale twist determining the handedness of the S-like chains. Chiroptical effects at the nexus of mechanics, excitonics and plasmonics open new operational principles for optical and optoelectronic devices from nanoparticles, carbon nanotubes and other nanoscale components. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | NATURE PUBLISHING GROUP | - |
dc.title | Reconfigurable chiroptical nanocomposites with chirality transfer from the macro- to the nanoscale | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yeom, Bongjun | - |
dc.identifier.doi | 10.1038/NMAT4525 | - |
dc.identifier.scopusid | 2-s2.0-84953206719 | - |
dc.identifier.wosid | 000372591700023 | - |
dc.identifier.bibliographicCitation | NATURE MATERIALS, v.15, no.4, pp.461 - 468 | - |
dc.relation.isPartOf | NATURE MATERIALS | - |
dc.citation.title | NATURE MATERIALS | - |
dc.citation.volume | 15 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 461 | - |
dc.citation.endPage | 468 | - |
dc.type.rims | ART | - |
dc.type.docType | 정기학술지(Article(Perspective Article포함)) | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | INTENSE OPTICAL-ACTIVITY | - |
dc.subject.keywordPlus | PLASMONIC NANOSTRUCTURES | - |
dc.subject.keywordPlus | CIRCULAR-DICHROISM | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | NANOROD | - |
dc.subject.keywordPlus | LIGHT | - |
dc.identifier.url | https://www.nature.com/articles/nmat4525 | - |
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