Molecular-Scale Interfacial Model for Predicting Electrode Performance in Rechargeable Batteries
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ming, Jun | - |
dc.contributor.author | Cao, Zhen | - |
dc.contributor.author | Li, Qian | - |
dc.contributor.author | Wahyudi, Wandi | - |
dc.contributor.author | Wang, Wenxi | - |
dc.contributor.author | Cavallo, Luigi | - |
dc.contributor.author | Park, Kang-Joon | - |
dc.contributor.author | Sun, Yang-Kook | - |
dc.contributor.author | Alshareef, Husam N. | - |
dc.date.accessioned | 2021-07-30T05:05:41Z | - |
dc.date.available | 2021-07-30T05:05:41Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2019-07 | - |
dc.identifier.issn | 2380-8195 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/2887 | - |
dc.description.abstract | It is commonly believed that the formation of a solid–electrolyte interphase (SEI) is the main reason for improved electrode performance in rechargeable batteries. However, herein we present a new interfacial model that may change the thinking about the role of SEI, which has prevailed over the past 2 decades. We show that the varied desolvation behavior of mobile ions, which depends on the solvation structure determined by multiple factors (e.g., cations, solvent, anions, and additives) is a critical factor for electrode stability besides the SEI. This interfacial model can predict the intercalating species in graphite electrodes (i.e., Li+ (de)intercalation or Li+–solvent co-insertion) in different types of electrolytes (e.g., carbonate-, ether-based electrolyte). The generality of our model is further demonstrated by its ability to interpret the variable lithium plating/stripping in different electrolytes. Our model can predict electrode performance through the proposed cation–solvent interactions and desolvation behaviors and then help develop new types of electrolytes for mobile (ion) batteries. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Molecular-Scale Interfacial Model for Predicting Electrode Performance in Rechargeable Batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Sun, Yang-Kook | - |
dc.identifier.doi | 10.1021/acsenergylett.9b00822 | - |
dc.identifier.scopusid | 2-s2.0-85068181333 | - |
dc.identifier.wosid | 000475827900013 | - |
dc.identifier.bibliographicCitation | ACS ENERGY LETTERS, v.4, no.7, pp.1584 - 1593 | - |
dc.relation.isPartOf | ACS ENERGY LETTERS | - |
dc.citation.title | ACS ENERGY LETTERS | - |
dc.citation.volume | 4 | - |
dc.citation.number | 7 | - |
dc.citation.startPage | 1584 | - |
dc.citation.endPage | 1593 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Electrochemistry | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Electrochemistry | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | LITHIUM METAL BATTERIES | - |
dc.subject.keywordPlus | CARBONATE-BASED ELECTROLYTES | - |
dc.subject.keywordPlus | LI-ION | - |
dc.subject.keywordPlus | FLUOROETHYLENE CARBONATE | - |
dc.subject.keywordPlus | VINYLENE CARBONATE | - |
dc.subject.keywordPlus | GRAPHITE-ELECTRODE | - |
dc.subject.keywordPlus | HIGH-VOLTAGE | - |
dc.subject.keywordPlus | INTERPHASE | - |
dc.subject.keywordPlus | ADDITIVES | - |
dc.subject.keywordPlus | CATHODE | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acsenergylett.9b00822 | - |
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