Biphasic silicon oxide nanocomposites as high-performance lithium storage materials
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Eunjun | - |
dc.contributor.author | Kim, Yeong Eun | - |
dc.contributor.author | Song, Juhye | - |
dc.contributor.author | Park, Min-Sik | - |
dc.contributor.author | Kim, Hansu | - |
dc.date.accessioned | 2021-07-30T05:05:43Z | - |
dc.date.available | 2021-07-30T05:05:43Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2019-07 | - |
dc.identifier.issn | 2050-7488 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/2892 | - |
dc.description.abstract | Silicon oxides (SiOx) have been widely explored as high-capacity lithium storage materials for lithium ion batteries (LIBs) due to the enhanced stability of their cycling performance compared to other Si-based materials. However, these materials suffer from insufficient electrochemical performance and reliability for commercial use in LIBs. Since the electrochemical performance of SiOx relies on microstructures and chemical compositions, we propose a material layout design of a biphasic SiOx composite that can achieve synergy between two different types of SiOx materials to improve electrochemical performance. Taking advantage of the properties of each component, a biphasic SiOx composite composed of silicon monoxide (SiO) and Si nanocrystals embedded in SiOx (Si/SiOx) exhibits notably improved electrochemical performance and suppressed volume expansion during cycling. The proposed biphasic material exhibits a high reversible capacity of 966 mA h g−1 with excellent long-term cycle performance for up to 350 cycles. With a core–shell structure, the biphasic Si/SiOx–SiO composite also has excellent dimensional stability. This approach presents a promising way to produce highly reliable high-capacity anode materials with a low production cost for mass production. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Biphasic silicon oxide nanocomposites as high-performance lithium storage materials | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Hansu | - |
dc.identifier.doi | 10.1039/c9ta04493k | - |
dc.identifier.scopusid | 2-s2.0-85068519542 | - |
dc.identifier.wosid | 000474271200010 | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY A, v.7, no.26, pp.15621 - 15626 | - |
dc.relation.isPartOf | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.citation.volume | 7 | - |
dc.citation.number | 26 | - |
dc.citation.startPage | 15621 | - |
dc.citation.endPage | 15626 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | HYDROGEN SILSESQUIOXANE | - |
dc.subject.keywordPlus | ANODE MATERIAL | - |
dc.subject.keywordPlus | ION BATTERIES | - |
dc.subject.keywordPlus | SIO | - |
dc.subject.keywordPlus | COMPOSITE | - |
dc.subject.keywordPlus | MONOXIDE | - |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2019/TA/C9TA04493K | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
222, Wangsimni-ro, Seongdong-gu, Seoul, 04763, Korea+82-2-2220-1365
COPYRIGHT © 2021 HANYANG UNIVERSITY.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.