The utilization of zinc recovered from alkaline battery waste as metal precursor in the synthesis of metal-organic framework
DC Field | Value | Language |
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dc.contributor.author | Vellingiri, Kowsalya | - |
dc.contributor.author | Tsang, Daniel C. W. | - |
dc.contributor.author | Kim, Ki-Hyun | - |
dc.contributor.author | Deep, Akash | - |
dc.contributor.author | Dutta, Tanushree | - |
dc.contributor.author | Boukhvalov, Danil W. | - |
dc.date.accessioned | 2021-07-30T05:06:52Z | - |
dc.date.available | 2021-07-30T05:06:52Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2018-10 | - |
dc.identifier.issn | 0959-6526 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/3027 | - |
dc.description.abstract | In the treatment of spent wastes, seeking extra economic incentives (e.g., through their regeneration into value-added end products) along with environmental protection is a highly ideal option to consider. In this context, a process was developed to utilize spent alkaline battery waste as a source medium of zinc (Zn2+) ions for the synthesis of a high-value material, metal organic frameworks (MOFs). For this purpose, multiple options including acid leaching and base precipitation were first compared for separation of Zn2+ ions from battery waste. Secondly, MOF-5 synthesis was carried out through two different routes: one using the Zn2+ ions separated from waste batteries (W-MOF-5) and the other using pure chemicals (P-MOF-5). Finally, differences in the structural properties (e.g., crystallinity and morphology) between the two MOF-5 types were assessed through characterization experiments (e.g., FTIR, PXRD, and SEM analyses) and modeling (DFT) studies. W-MOF-5 was found to possess tetragonal lattice parameters which indicated decrease in the Zn2+ ions in the framework. This deficiency increased the interplanar Bragg angles which led to the different size and shape of W-MOF-5. Also, the PXRD spectrum indicated the presence of all peaks at similar position with that of P-MOF-5. Additionally, the preparation of 1 kg of W-MOF-5 requires a low cost (42 USD) when one considers >90% of solvent recovery. Also in terms of materials cost, the synthesis of W-MOF-5 was highly cost-effective than that of ZnO nanoparticles. In light of many compatibilities between MOFs synthesized through the two different routes, the method proposed in this work can be further developed toward a simple, fast, and reliable route for MOF-5 production from battery waste. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCI LTD | - |
dc.title | The utilization of zinc recovered from alkaline battery waste as metal precursor in the synthesis of metal-organic framework | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Ki-Hyun | - |
dc.identifier.doi | 10.1016/j.jclepro.2018.07.233 | - |
dc.identifier.scopusid | 2-s2.0-85053204098 | - |
dc.identifier.wosid | 000444358400090 | - |
dc.identifier.bibliographicCitation | JOURNAL OF CLEANER PRODUCTION, v.199, pp.995 - 1006 | - |
dc.relation.isPartOf | JOURNAL OF CLEANER PRODUCTION | - |
dc.citation.title | JOURNAL OF CLEANER PRODUCTION | - |
dc.citation.volume | 199 | - |
dc.citation.startPage | 995 | - |
dc.citation.endPage | 1006 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalResearchArea | Environmental Sciences & Ecology | - |
dc.relation.journalWebOfScienceCategory | Green & Sustainable Science & Technology | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Environmental Sciences | - |
dc.subject.keywordPlus | ROOM-TEMPERATURE SYNTHESIS | - |
dc.subject.keywordPlus | ZNO NANOPARTICLES | - |
dc.subject.keywordPlus | SPENT ALKALINE | - |
dc.subject.keywordPlus | MOF-5 | - |
dc.subject.keywordPlus | NANOCOMPOSITES | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | SEPARATION | - |
dc.subject.keywordPlus | POWDER | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | PARTICLES | - |
dc.subject.keywordAuthor | MOF-5 | - |
dc.subject.keywordAuthor | Waste valorization | - |
dc.subject.keywordAuthor | Zn recovery | - |
dc.subject.keywordAuthor | Precipitation-assisted synthesis | - |
dc.subject.keywordAuthor | Regeneration | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0959652618322224?via%3Dihub | - |
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