2-(N-Methylbenzyl)pyridine: A Potential Liquid Organic Hydrogen Carrier with Fast H₂ Release and Stable Activity in Consecutive Cycles
DC Field | Value | Language |
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dc.contributor.author | Oh, Jinho | - |
dc.contributor.author | Jeong, Kwanyong | - |
dc.contributor.author | Kim, Tae Wan | - |
dc.contributor.author | Kwon, Hyunguk | - |
dc.contributor.author | Han, Jeong Woo | - |
dc.contributor.author | Park, Ji Hoon | - |
dc.contributor.author | Suh, Young-Woong | - |
dc.date.accessioned | 2021-08-03T03:27:04Z | - |
dc.date.available | 2021-08-03T03:27:04Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2018-02 | - |
dc.identifier.issn | 1864-5631 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/32999 | - |
dc.description.abstract | The liquid organic hydrogen carrier (LOHC) 2-(N-methylbenzyl)pyridine (MBP) shows good potential for H-2 storage based on reversible hydrogenation and dehydrogenation, with an H-2 storage density of 6.15wt%. This material and the corresponding perhydro product (H-12-MBP) are liquids at room temperature. Remarkably, H-2 release is much faster from H-12-MBP over Pd/C than from the benchmark perhydro benzyltoluene over Pt/C at lower temperatures than 270 degrees C, owing to the addition of N atom into the benzene ring. Since this positive effect is unfavorable to the hydrogenation reaction, more Ru/Al2O3 catalyst or prolonged reaction time must be applied for complete H-2 storage. Experiments with repeated hydrogenation-dehydrogenation cycles reveal that reversible H-2 storage and release are possible without degradation of the MBP/H-12-MBP pair. The prepared MBP satisfies the requirements for chemical stability, handling properties, and cytotoxicity testing. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | 2-(N-Methylbenzyl)pyridine: A Potential Liquid Organic Hydrogen Carrier with Fast H₂ Release and Stable Activity in Consecutive Cycles | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Suh, Young-Woong | - |
dc.identifier.doi | 10.1002/cssc.201702256 | - |
dc.identifier.scopusid | 2-s2.0-85040734202 | - |
dc.identifier.wosid | 000425730600002 | - |
dc.identifier.bibliographicCitation | CHEMSUSCHEM, v.11, no.4, pp.661 - 665 | - |
dc.relation.isPartOf | CHEMSUSCHEM | - |
dc.citation.title | CHEMSUSCHEM | - |
dc.citation.volume | 11 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 661 | - |
dc.citation.endPage | 665 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Green & Sustainable Science & Technology | - |
dc.subject.keywordPlus | DODECAHYDRO-N-ETHYLCARBAZOLE | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | DEHYDROGENATION | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | PD | - |
dc.subject.keywordPlus | SYSTEMS | - |
dc.subject.keywordPlus | LOHC | - |
dc.subject.keywordAuthor | dehydrogenation | - |
dc.subject.keywordAuthor | heterocycles | - |
dc.subject.keywordAuthor | hydrogen storage | - |
dc.subject.keywordAuthor | sustainable chemistry | - |
dc.identifier.url | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.201702256 | - |
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