New Forms of CdSe: Molecular Wires, Gels, and Ordered Mesoporous Assemblies
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hudson, Margaret H. | - |
dc.contributor.author | Dolzhnikov, Dmitriy S. | - |
dc.contributor.author | Filatov, Alexander S. | - |
dc.contributor.author | Janke, Eric M. | - |
dc.contributor.author | Jang, Jaeyoung | - |
dc.contributor.author | Lee, Byeongdu | - |
dc.contributor.author | Sun, Chengjun | - |
dc.contributor.author | Talapin, Dmitri V. | - |
dc.date.accessioned | 2021-07-30T05:25:57Z | - |
dc.date.available | 2021-07-30T05:25:57Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2017-03 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/4808 | - |
dc.description.abstract | This work investigates the structure and properties of soluble chalcogenidocadmates, a molecular form of cadmium chalcogenides with unprecedented one-dimensional bonding motifs. The single crystal X-ray structure reveals that sodium selenocadmate consists of infinite one-dimensional wires of (Cd2Se3)(n)2(n-) charge balanced by Na+ and stabilized by coordinating solvent molecules. Exchanging the sodium cation with tetraethylammonium or didodecyldimethylammonium expands the versatility of selenocadmate by improving its solubility in a variety of polar and nonpolar solvents without changing the anion structure and properties. The introduction of a micelle-forming cationic surfactant allows for the templating of selenocadmate, or the analogous telluride species, to create ordered organic-inorganic hybrid CdSe or CdTe mesostructures. Finally, the interaction of selenocadmate "wires" with Cd2+ ions creates an unprecedented gel-like form of stoichiometric CdSe. We also demonstrate that these low-dimensional CdSe species show characteristic semiconductor behavior, and can be used in photodetectors and field-effect transistors. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | New Forms of CdSe: Molecular Wires, Gels, and Ordered Mesoporous Assemblies | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Jang, Jaeyoung | - |
dc.identifier.doi | 10.1021/jacs.6b10077 | - |
dc.identifier.scopusid | 2-s2.0-85014716659 | - |
dc.identifier.wosid | 000396185700016 | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.139, no.9, pp.3368 - 3377 | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 139 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 3368 | - |
dc.citation.endPage | 3377 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | FIELD-EFFECT TRANSISTORS | - |
dc.subject.keywordPlus | COLLOIDAL NANOCRYSTALS | - |
dc.subject.keywordPlus | QUANTUM DOTS | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | METAL CHALCOGENIDES | - |
dc.subject.keywordPlus | PORE ORGANIZATION | - |
dc.subject.keywordPlus | SCALE SYNTHESIS | - |
dc.subject.keywordPlus | GAS SEPARATION | - |
dc.subject.keywordPlus | SEEDED GROWTH | - |
dc.subject.keywordPlus | CDE E | - |
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