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Radical Fragmentation of 4a-hydroxy-octahydronaphthalen-1-one Derived from 3,5-Dibromopyrone: Synthesis of Various Medium-Sized Rings
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | 조천규 | - |
| dc.date.accessioned | 2021-08-04T04:24:51Z | - |
| dc.date.available | 2021-08-04T04:24:51Z | - |
| dc.date.issued | 2005-08-25 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/72016 | - |
| dc.description.abstract | Beta-Hydroxyketones derived from Diels-Alder reaction of 3,5-dibromopyrone were tested in several ring-enlargement reactions. We found that photolysis of beta-hydroxyketone 2 in the presence of HgO and I2 rsults in beta-alkoxy radical, which undergo desired fragmentation. Alpha-carbonyl radical thus generated is trapped by molecular iodine to give alpha-iodo ketone medium-ring 3. | - |
| dc.title | Radical Fragmentation of 4a-hydroxy-octahydronaphthalen-1-one Derived from 3,5-Dibromopyrone: Synthesis of Various Medium-Sized Rings | - |
| dc.type | Conference | - |
| dc.citation.conferenceName | 11th Asian Chemical Congress | - |
| dc.citation.conferencePlace | 고려대학교 | - |
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Related Researcher
- Cho, Cheon Gyu
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)