Metal-organic framework as a photocatalyst: Progress in modulation strategies and environmental/energy applications
DC Field | Value | Language |
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dc.contributor.author | Younis, Sherif A. | - |
dc.contributor.author | Kwon, Eilhann E. | - |
dc.contributor.author | Qasim, Muhammad | - |
dc.contributor.author | Kim, Ki-Hyun | - |
dc.contributor.author | Kim, Taejin | - |
dc.contributor.author | Kukkar, Deepak | - |
dc.contributor.author | Dou, Xiaomin | - |
dc.contributor.author | Ali, Imran | - |
dc.date.accessioned | 2021-08-02T08:50:57Z | - |
dc.date.available | 2021-08-02T08:50:57Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2020-11 | - |
dc.identifier.issn | 0360-1285 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/8816 | - |
dc.description.abstract | Progress in the design, synthesis, and modification of metal-organic frameworks (MOFs) has immensely helped expand their applications in a wide variety of research fields. Such developments offered great opportunities for upgrading their efficiencies in diverse photocatalytic applications (e.g., N-2/CO2 reduction, H-2 generation, organic synthesis, and environmental remediation) through enhanced conversion/storage of solar energy. The MOF-based photocatalytic platforms are, nonetheless, subject to many practical problems (e.g., inapplicability for industrial upscaling and thermodynamic instability under environmental conditions). In this review, the effects of synthesis/modification strategies on MOF photocatalysis have been discussed with respect to the type of inorganic nodes, the modulation of organic ligands, and the pre-/post-synthesis modification in MOF networks (i.e., MOF-based composite). Particular emphasis was placed on the technical advances achieved in the photoelectronic/catalytic performances of MOFs in multiple energy/environmental (redox) reactions based on both experimental and theoritical analyses. Further, the technical merits/disadvantages of MOF photocatalysts (in terms of structural defects, light absorption, active sites, and kinetic/thermodynamic stability) have been evaluated in relation to quantum efficiency and charge transfer mechanisms in various photo-redox reactions. The pursuit of strategies for enhanced kinetic stability of MOFs have also been highlighted based on the nature/strength of coordination modes, the inertness of metal centers, and the functionality of ligand types. Lastly, the current limitations of MOF-based photocatalysts are addressed with respect to their practical applications at industrial scales along with a discussion on their future use. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.title | Metal-organic framework as a photocatalyst: Progress in modulation strategies and environmental/energy applications | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Ki-Hyun | - |
dc.identifier.doi | 10.1016/j.pecs.2020.100870 | - |
dc.identifier.scopusid | 2-s2.0-85087490891 | - |
dc.identifier.wosid | 000566944100006 | - |
dc.identifier.bibliographicCitation | PROGRESS IN ENERGY AND COMBUSTION SCIENCE, v.81, pp.1 - 49 | - |
dc.relation.isPartOf | PROGRESS IN ENERGY AND COMBUSTION SCIENCE | - |
dc.citation.title | PROGRESS IN ENERGY AND COMBUSTION SCIENCE | - |
dc.citation.volume | 81 | - |
dc.citation.startPage | 1 | - |
dc.citation.endPage | 49 | - |
dc.type.rims | ART | - |
dc.type.docType | Review | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Thermodynamics | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Thermodynamics | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.relation.journalWebOfScienceCategory | Engineering, Mechanical | - |
dc.subject.keywordPlus | ZEOLITIC IMIDAZOLATE FRAMEWORKS | - |
dc.subject.keywordPlus | PRESSURE-INDUCED AMORPHIZATION | - |
dc.subject.keywordPlus | IN-SITU SYNTHESIS | - |
dc.subject.keywordPlus | VISIBLE-LIGHT | - |
dc.subject.keywordPlus | HYDROGEN-PRODUCTION | - |
dc.subject.keywordPlus | BAND-GAP | - |
dc.subject.keywordPlus | EFFICIENT PHOTOCATALYSTS | - |
dc.subject.keywordPlus | NITROGEN-FIXATION | - |
dc.subject.keywordPlus | CO2 REDUCTION | - |
dc.subject.keywordPlus | INTEGRATED ADSORPTION | - |
dc.subject.keywordAuthor | Metal-organic frameworks (MOFs) | - |
dc.subject.keywordAuthor | Electronic/optical behaviors | - |
dc.subject.keywordAuthor | Computational analysis | - |
dc.subject.keywordAuthor | Modulation photosensitization | - |
dc.subject.keywordAuthor | Environmental/energy photocatalysis | - |
dc.subject.keywordAuthor | Kinetic/thermodynamic stability | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0360128520300800?via%3Dihub | - |
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