Engineering Sodium-Ion Solvation Structure to Stabilize Sodium Anodes: Universal Strategy for Fast-Charging and Safer Sodium-Ion Batteries
DC Field | Value | Language |
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dc.contributor.author | Zhou, Lin | - |
dc.contributor.author | Cao, Zhen | - |
dc.contributor.author | Zhang, Jiao | - |
dc.contributor.author | Sun, Qujiang | - |
dc.contributor.author | Wu, Yingqiang | - |
dc.contributor.author | Wahyudi, Wandi | - |
dc.contributor.author | Hwang, Jang-Yeon | - |
dc.contributor.author | Wang, Limin | - |
dc.contributor.author | Cavallo, Luigi | - |
dc.contributor.author | Sun, Yang-Kook | - |
dc.contributor.author | Alshareef, Husam N. | - |
dc.contributor.author | Ming, Jun | - |
dc.date.accessioned | 2021-08-02T09:28:05Z | - |
dc.date.available | 2021-08-02T09:28:05Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2020-05 | - |
dc.identifier.issn | 1530-6984 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/9854 | - |
dc.description.abstract | Sodium-ion batteries are promising alternatives for lithium-ion batteries due to their lower cost caused by global sodium availability. However, the low Coulombic efficiency (CE) of the sodium metal plating/stripping process represents a serious issue for the Na anode, which hinders achieving a higher energy density. Herein, we report that the Na+ solvation structure, particularly the type and location of the anions, plays a critical role in determining the Na anode performance. We show that the low CE results from anion-mediated corrosion, which can be tackled readily through tuning the anion interaction at the electrolyte/anode interface. Our strategy thus enables fast-charging Na-ion and Na–S batteries with a remarkable cycle life. The presented insights differ from the prevailing interpretation that the failure mechanism mostly results from sodium dendrite growth and/or solid electrolyte interphase formation. Our anionic model introduces a new guideline for improving the electrolytes for metal-ion batteries with a greater energy density. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Engineering Sodium-Ion Solvation Structure to Stabilize Sodium Anodes: Universal Strategy for Fast-Charging and Safer Sodium-Ion Batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Sun, Yang-Kook | - |
dc.identifier.doi | 10.1021/acs.nanolett.9b05355 | - |
dc.identifier.scopusid | 2-s2.0-85084696087 | - |
dc.identifier.wosid | 000535255300040 | - |
dc.identifier.bibliographicCitation | NANO LETTERS, v.20, no.5, pp.3247 - 3254 | - |
dc.relation.isPartOf | NANO LETTERS | - |
dc.citation.title | NANO LETTERS | - |
dc.citation.volume | 20 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 3247 | - |
dc.citation.endPage | 3254 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | LITHIUM-ION | - |
dc.subject.keywordPlus | METAL ANODES | - |
dc.subject.keywordPlus | ELECTROLYTES | - |
dc.subject.keywordPlus | NA | - |
dc.subject.keywordPlus | INSIGHTS | - |
dc.subject.keywordPlus | DIGLYME | - |
dc.subject.keywordPlus | MODEL | - |
dc.subject.keywordAuthor | sodium battery | - |
dc.subject.keywordAuthor | electrolyte | - |
dc.subject.keywordAuthor | solid electrolyte interphase | - |
dc.subject.keywordAuthor | anode | - |
dc.subject.keywordAuthor | fast charging | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.nanolett.9b05355 | - |
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