Efficient hydrogen charge into monobenzyltoluene over Ru/MgO catalysts synthesized by thermolysis of Ru₃(CO)₁₂ on porous Mg(OH)₂ powder
DC Field | Value | Language |
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dc.contributor.author | Kim, Tae Wan | - |
dc.contributor.author | Ko, Sang Hyeok | - |
dc.contributor.author | Kim, Minseok | - |
dc.contributor.author | Suh, Young-Woong | - |
dc.date.accessioned | 2021-08-02T09:28:51Z | - |
dc.date.available | 2021-08-02T09:28:51Z | - |
dc.date.created | 2021-05-12 | - |
dc.date.issued | 2020-04 | - |
dc.identifier.issn | 0921-8831 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/9923 | - |
dc.description.abstract | MgO-supported Ru catalysts for H₂ charge into monobenzyltoluene, which is a liquid organic hydrogen carrier, were developed by treating the precipitated Mg(OH)₂ with different methods, namely calcination and hydration, followed by the thermolysis of Ru₃(CO)₁₂-loaded samples under identical conditions. The subsequent investigations revealed that the H₂ storage efficiency depended on the surface atomic ratio of Ru/Mg and basicity of the synthesized catalysts that exhibited similar levels of Ru dispersion. In contrast, the Ru/MgO prepared from commercial Mg(OH)₂ exhibited inferior catalytic performance to the synthesized analogue, owing to its low Ru dispersion. All the presented results suggested that the surface OH-intact Mg(OH)₂ with a fairly high surface area and large pores is required for the synthesis of a highly active Ru/MgO catalyst via thermolysis of Ru₃(CO)₁₂. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER | - |
dc.title | Efficient hydrogen charge into monobenzyltoluene over Ru/MgO catalysts synthesized by thermolysis of Ru₃(CO)₁₂ on porous Mg(OH)₂ powder | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Suh, Young-Woong | - |
dc.identifier.doi | 10.1016/j.apt.2020.02.012 | - |
dc.identifier.scopusid | 2-s2.0-85079903861 | - |
dc.identifier.wosid | 000542644800002 | - |
dc.identifier.bibliographicCitation | ADVANCED POWDER TECHNOLOGY, v.31, no.4, pp.1682 - 1692 | - |
dc.relation.isPartOf | ADVANCED POWDER TECHNOLOGY | - |
dc.citation.title | ADVANCED POWDER TECHNOLOGY | - |
dc.citation.volume | 31 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 1682 | - |
dc.citation.endPage | 1692 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | SUPPORTED RUTHENIUM CATALYSTS | - |
dc.subject.keywordPlus | AMMONIA-SYNTHESIS | - |
dc.subject.keywordPlus | MAGNESIUM-OXIDE | - |
dc.subject.keywordPlus | ORGANOMETALLIC CHEMISTRY | - |
dc.subject.keywordPlus | SURFACE-STRUCTURE | - |
dc.subject.keywordPlus | CARRIER LOHC | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | MGO | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordAuthor | Hydrogenation | - |
dc.subject.keywordAuthor | Liquid organic hydrogen carrier | - |
dc.subject.keywordAuthor | MgO | - |
dc.subject.keywordAuthor | Supported Ru catalyst | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0921883120300649?via%3Dihub | - |
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