Improvement in the thermoelectric performance of highly reproducible n-type (Bi,Sb)(2)Se(3)alloys by Cl-doping
DC Field | Value | Language |
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dc.contributor.author | Nasir, Nadra | - |
dc.contributor.author | Lee, Kyu Hyoung | - |
dc.contributor.author | Kim, Sang-il | - |
dc.contributor.author | Kim, Hyun-Sik | - |
dc.contributor.author | Lim, Jae-Hong | - |
dc.contributor.author | Fu, Liangwei | - |
dc.contributor.author | Kim, Sung Wng | - |
dc.date.available | 2021-03-17T06:53:04Z | - |
dc.date.created | 2021-02-26 | - |
dc.date.issued | 2020-06 | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/11677 | - |
dc.description.abstract | (Bi,Sb)(2)Se(3)alloys are promising alternatives to commercial n-type Bi-2(Te,Se)(3)ingots for low-mid temperature thermoelectric power generation due to their high thermoelectric conversion efficiency at elevated temperatures. Herein, we report the enhanced high-temperature thermoelectric performance of the polycrystalline Cl-doped Bi2-xSbxSe3(x= 0.8, 1.0) bulks and their sustainable thermal stability. Significant role of Cl substitution, characterized to enhance the power factor and reduce the thermal conductivity synergetically, is clearly elucidated. Cl-doping at Se-site of both Bi(1.2)Sb(0.8)Se(3)and BiSbSe(3)results in a high power factor by carrier generation and Hall mobility improvement while maintaining converged electronic band valleys. Furthermore, point defect phonon scattering originated from mass fluctuations formed at Cl-substituted Se-sites reduces the lattice thermal conductivity. Most importantly, spark plasma sintered Cl-doped Bi(2-x)Sb(x)Se(3)bulks are thermally stable up to 700 K, and show a reproducible maximum thermoelectric figure of merit,zT, of 0.68 at 700 K. | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Improvement in the thermoelectric performance of highly reproducible n-type (Bi,Sb)(2)Se(3)alloys by Cl-doping | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Hyun-Sik | - |
dc.identifier.doi | 10.1039/d0ra04065g | - |
dc.identifier.scopusid | 2-s2.0-85087543299 | - |
dc.identifier.wosid | 000544898700056 | - |
dc.identifier.bibliographicCitation | RSC ADVANCES, v.10, no.41, pp.24663 - 24668 | - |
dc.relation.isPartOf | RSC ADVANCES | - |
dc.citation.title | RSC ADVANCES | - |
dc.citation.volume | 10 | - |
dc.citation.number | 41 | - |
dc.citation.startPage | 24663 | - |
dc.citation.endPage | 24668 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
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