Synthesis and Band Gap Analysis of Designed Porphyrin Derivatives Containing Electron Donating and Accepting Group
DC Field | Value | Language |
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dc.contributor.author | Chang, In-Jung | - |
dc.contributor.author | Jeon, Yea-Sel | - |
dc.contributor.author | Hwang, Kwang-Jin | - |
dc.date.available | 2020-07-10T04:02:06Z | - |
dc.date.created | 2020-07-06 | - |
dc.date.issued | 2019-02 | - |
dc.identifier.issn | 1229-5949 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/1997 | - |
dc.description.abstract | Symmetric (DD, AA1-AA5) and non-symmetric (DA1) porphyrin derivatives were synthesized through McDonald coupling of bispyrrole 2D, 2A1-2A5 with the corresponding aldehyde 3 or diol 6 as a key step. The UV-Vis spectrum and CV of those porphyrins were measured and analyzed for band gap and HOMO-LUMO energy. With the electron withdrawing group, the band gap of porphyrins PP was increased and that of metalloporphyrin PP-M decreased. The HOMO level of PP and LUMO level of PP-M were more lowered than the LUMO of PP and the HOMO of PP-M, respectively. The LUMO level of all PP and PP-M was lower than that of P3HT (-2.80 eV) and all HOMO energy of PP and PP-M was higher than that of PCBM (-6.20 eV). | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | BUILDING-BLOCKS | - |
dc.title | Synthesis and Band Gap Analysis of Designed Porphyrin Derivatives Containing Electron Donating and Accepting Group | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Hwang, Kwang-Jin | - |
dc.identifier.doi | 10.1002/bkcs.11680 | - |
dc.identifier.scopusid | 2-s2.0-85061280357 | - |
dc.identifier.wosid | 000459209000018 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.40, no.2, pp.173 - 179 | - |
dc.relation.isPartOf | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 40 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 173 | - |
dc.citation.endPage | 179 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART002437578 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | BUILDING-BLOCKS | - |
dc.subject.keywordAuthor | porphyrin | - |
dc.subject.keywordAuthor | band gap | - |
dc.subject.keywordAuthor | organic photovoltaic cell | - |
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