Synthesis and Fragmentation of Furoxanaldehydes in the Gas Phase for Nanopatterned Alkyne Formation on a Solid Surface
DC Field | Value | Language |
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dc.contributor.author | Kim, Gi Young | - |
dc.contributor.author | Kim, Jucheon | - |
dc.contributor.author | Lee, Seung Hee | - |
dc.contributor.author | Kim, Hyung Jin | - |
dc.contributor.author | Hwang, Kwang-Jin | - |
dc.date.accessioned | 2022-01-03T05:44:02Z | - |
dc.date.available | 2022-01-03T05:44:02Z | - |
dc.date.created | 2021-12-28 | - |
dc.date.issued | 2009-02-20 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/21906 | - |
dc.description.abstract | Furoxanaldellydes possessing phenyl or alkenyl groups at the 3- or 4-position of the furoxan ring were designed for alkyne formation on a solid surface. Furoxans 2 and 3 were prepared from the corresponding alkenes 2a and 3a by the reaction with NaNO2 in acetic acid. Furoxan 4, in which the furoxan ring is conjugated with a double bond, was prepared from bis(bromomethyl)benzene 4a in 5 steps using the Wittig reaction of aldehyde I as the key step. The electron beam-mediated fragmentation of furoxanaldehydes 1-4 in a mass spectrometer was exploited by focusing on alkyne formation on the solid surface. The fragmentation of furoxan 3 possessing diaryl groups afforded diaryl-acetylene at high efficiency, suggesting that the aryl group conjugated with the furoxan ring could facilitate alkyne formation with the evolution of NO. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | UNSYMMETRICALLY SUBSTITUTED FUROXANS | - |
dc.subject | NITRIC-OXIDE | - |
dc.subject | PROTEIN IMMOBILIZATION | - |
dc.subject | ELECTRON-BEAM | - |
dc.subject | L-ARGININE | - |
dc.subject | RELEASE | - |
dc.subject | CARBOHYDRATE | - |
dc.subject | DERIVATIVES | - |
dc.subject | REACTIVITY | - |
dc.subject | MONOLAYERS | - |
dc.title | Synthesis and Fragmentation of Furoxanaldehydes in the Gas Phase for Nanopatterned Alkyne Formation on a Solid Surface | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lee, Seung Hee | - |
dc.contributor.affiliatedAuthor | Hwang, Kwang-Jin | - |
dc.identifier.wosid | 000264903700038 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.30, no.2, pp.459 - 463 | - |
dc.relation.isPartOf | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 30 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 459 | - |
dc.citation.endPage | 463 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART001524505 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | UNSYMMETRICALLY SUBSTITUTED FUROXANS | - |
dc.subject.keywordPlus | NITRIC-OXIDE | - |
dc.subject.keywordPlus | PROTEIN IMMOBILIZATION | - |
dc.subject.keywordPlus | ELECTRON-BEAM | - |
dc.subject.keywordPlus | L-ARGININE | - |
dc.subject.keywordPlus | RELEASE | - |
dc.subject.keywordPlus | CARBOHYDRATE | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | MONOLAYERS | - |
dc.subject.keywordAuthor | Alkyne | - |
dc.subject.keywordAuthor | Furoxan | - |
dc.subject.keywordAuthor | Furoxanaldehyde | - |
dc.subject.keywordAuthor | E-beam | - |
dc.subject.keywordAuthor | Fragmentation | - |
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