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Interaction of organonitriles with electron rich calix[4]arene derivatives on gold substrates
- Authors
- Kim, Wan-Sang; Shin, Dong-Myung; Chung, Gee-Won
- Issue Date
- Mar-2007
- Publisher
- TAYLOR & FRANCIS LTD
- Keywords
- calix[4] arene; self-assembled monolayer; surface plasmon resonance
- Citation
- MOLECULAR CRYSTALS AND LIQUID CRYSTALS, v.464, pp.675 - 683
- Journal Title
- MOLECULAR CRYSTALS AND LIQUID CRYSTALS
- Volume
- 464
- Start Page
- 675
- End Page
- 683
- ISSN
- 1542-1406
- Abstract
- We synthesized 25,26,27,28- tetrakis( mercaptobuthoxy)- 5,11,17,23-[ 2,20- thioxy( ophenylene) thioxy- piperidino] calix[ 4] arene [ 1], 25,26,27,28- tetrakis( mercaptobuthoxy)5,11,17,23-[ 2,20- thioxy( o- phenylene) thioxy- amino] calix[ 4] arene [ 2] and 25,26,27,28tetrakis( mercaptobuthoxy)- 5,11,17,23-[ 2,20- thioxy( o- phenylene) thioxy- aminopyrene] calix[ 4] arene [ 3] containing four alkyl thiol linkages, which allow the calix[ 4] arene to attach on the gold surface. We observed the binding of calix[ 4] arene derivatives and aromatic molecules with surface plasmon resonance and confirmed complexation of aromatic nitriles on calix[ 4] arene derivatives with FT- IR peak.
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Collections - College of Engineering > Chemical Engineering Major > 1. Journal Articles
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