Iridium(III) complexes with 6-pentafluorophenyl-2, 4-diphenylquinolines for red OLEDs
DC Field | Value | Language |
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dc.contributor.author | Park, Gui Youn | - |
dc.contributor.author | Seo, Ji Hyun | - |
dc.contributor.author | Kim, Young Kwan | - |
dc.contributor.author | Kim, Young Sik | - |
dc.date.accessioned | 2022-01-14T09:44:15Z | - |
dc.date.available | 2022-01-14T09:44:15Z | - |
dc.date.created | 2022-01-14 | - |
dc.date.issued | 2007 | - |
dc.identifier.issn | 1542-1406 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/24305 | - |
dc.description.abstract | Novel red electrophosphorescent devices were fabricated by doping perfluorophenyl substituted iridium( III) complex, bis[ 1-( 6- Pentafluorophenyl- 2,4- diphenyl) quinolinato-N, C-2'] iridium( III) ( acetylacetonate) [ Ir( PF- dpq)(2)( acac)] for the application in organic light- emitting diodes ( OLEDs). The maximum electroluminescent ( EL) wavelengths of Ir( dpq)(2)( acac) and Ir( PF- dpq)(2)( acac) have shown at 614nm and 620 nm, respectively. The device using Ir( PF- dpq) 2( acac) showed red emission with 1931 CIE chromaticity coordinates ( x= 0.640, y= 0.342) at 12 V. The perfluorophenyl substituent on the quinoline ring as electron withdrawing group decreased the lowest unoccupied molecular orbital ( LOMO). As a result, the energy gap is reduced, leading to red- shift the emission wavelength. The ab initio calculation using the time- dependent density function theory ( DFT) showed in agreement with the experimental results. However, the iridium complex of PF- dpq underwent a weak MLCT transition because of the weak coupling between the 5d- orbital of the iridium atom and HOMO of the substituted ligand. Thus, the luminous efficiency of the device using Ir( dpq)(2)( acac) and Ir( PF- dpq)(2)( acac) are 4.36 cd/A and 3.13 cd/A, respectively, at the current density of 3.38mA= cm(2) and 1.11mA/cm(2). | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | TAYLOR & FRANCIS LTD | - |
dc.subject | LIGHT-EMITTING-DIODES | - |
dc.subject | DEVICES | - |
dc.title | Iridium(III) complexes with 6-pentafluorophenyl-2, 4-diphenylquinolines for red OLEDs | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Young Kwan | - |
dc.contributor.affiliatedAuthor | Kim, Young Sik | - |
dc.identifier.doi | 10.1080/15421400701548530 | - |
dc.identifier.scopusid | 2-s2.0-34848863618 | - |
dc.identifier.wosid | 000250039700034 | - |
dc.identifier.bibliographicCitation | MOLECULAR CRYSTALS AND LIQUID CRYSTALS, v.471, pp.293 - 303 | - |
dc.relation.isPartOf | MOLECULAR CRYSTALS AND LIQUID CRYSTALS | - |
dc.citation.title | MOLECULAR CRYSTALS AND LIQUID CRYSTALS | - |
dc.citation.volume | 471 | - |
dc.citation.startPage | 293 | - |
dc.citation.endPage | 303 | - |
dc.type.rims | ART | - |
dc.type.docType | Article; Proceedings Paper | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Crystallography | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | LIGHT-EMITTING-DIODES | - |
dc.subject.keywordPlus | DEVICES | - |
dc.subject.keywordAuthor | DFT | - |
dc.subject.keywordAuthor | 2,4-diphenylquinoline ligand | - |
dc.subject.keywordAuthor | iridium complex | - |
dc.subject.keywordAuthor | OLED | - |
dc.subject.keywordAuthor | phosphorescence | - |
dc.subject.keywordAuthor | red | - |
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