Integration of Exciton Donor and Acceptor in a Blue-Emitting Molecule with Zero Radius of Intramolecular Energy Transfer Mechanism for Highly Efficient and Stable Fluorescent OLEDs
DC Field | Value | Language |
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dc.contributor.author | Park, Bubae | - |
dc.contributor.author | Kim, Ki Ju | - |
dc.contributor.author | Nam, Hyewon | - |
dc.contributor.author | Park, Bum Joon | - |
dc.contributor.author | Kang, Sunwoo | - |
dc.contributor.author | Oh, Hyoung Yun | - |
dc.contributor.author | Kim, Taekyung | - |
dc.date.accessioned | 2023-05-22T02:40:21Z | - |
dc.date.available | 2023-05-22T02:40:21Z | - |
dc.date.issued | 2023-01-01 | - |
dc.identifier.issn | 2195-1071 | - |
dc.identifier.issn | 2195-1071 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/31159 | - |
dc.description.abstract | Multimaterial emission layer (EML) with host and dopant is known for its advantages in efficiency and lifetime for organic light-emitting diodes (OLEDs). However, as the compositions and the mixing ratio in the EML diversify, complex device physics and photophysics and complicated fabrication processes become challenging issues. Herein, a new concept to integrate exciton donor (host) and acceptor (dopant) into a single emitting molecule is suggested. 9-(8,9,10,11-Tetradeuterospiro[benzo[de]anthracene-7,9 '-fluoren]-2'-yl)-9H-carbazole (SBAF-Cz) and 8,9,10,11-tetradeutero-N-(9,9-dimethyl-9H-fluoren-2-yl)-N-phenylspiro[benzo[de]anthracene-7,9 '-fluoren]-3-amine (FPA-SBAF) are used as host and dopant, respectively. By integrating two units, 8,9,10,11-tetradeutero-2 '-(9H-carbazol-9-yl)-N-(9,9-dimethyl-9H-fluoren-2-yl)-N-phenylspiro[benzo[de]anthracene-7,9 '-fluoren]-3-amine (FPA-SBAF-Cz) is synthesized, and photophysical and electrical properties are characterized. Density functional theory and experimental results consistently reveal that SBAF-Cz and FPA-SBAF are photophysically and electrically independent. The electrical properties of FPA-SBAF-Cz behave independently, while the photophysical properties are the sum of those of SBAF-Cz and FPA-SBAF, which is attributed to the zero radius of intramolecular energy transfer (ZRIET) between donor and acceptor in FPA-SBAF-Cz. The single-component blue OLED with FPA-SBAF-Cz exhibits a maximum external quantum efficiency of 4.18%, which is higher than those of OLEDs with SBAF-CZ:FPA-SBAF multicomponent EMLs. Surprisingly, the device lifetime to 50% decrease from initial luminance is 114 h in FPA-SBAF-Cz OLED, which is 2.2 times longer than that of SBAF-Cz:FPA-SBAF OLEDs. | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Integration of Exciton Donor and Acceptor in a Blue-Emitting Molecule with Zero Radius of Intramolecular Energy Transfer Mechanism for Highly Efficient and Stable Fluorescent OLEDs | - |
dc.type | Article | - |
dc.publisher.location | 독일 | - |
dc.identifier.doi | 10.1002/adom.202300291 | - |
dc.identifier.scopusid | 2-s2.0-85154041218 | - |
dc.identifier.wosid | 000975735200001 | - |
dc.identifier.bibliographicCitation | ADVANCED OPTICAL MATERIALS, v.11, no.15 | - |
dc.citation.title | ADVANCED OPTICAL MATERIALS | - |
dc.citation.volume | 11 | - |
dc.citation.number | 15 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Optics | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Optics | - |
dc.subject.keywordPlus | FUSED-RING | - |
dc.subject.keywordPlus | DIODES | - |
dc.subject.keywordPlus | ELECTROLUMINESCENCE | - |
dc.subject.keywordAuthor | intramolecular energy transfer | - |
dc.subject.keywordAuthor | organic light-emitting diodes | - |
dc.subject.keywordAuthor | zero radius | - |
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