Synthesis and Band Gap Analysis of Meso-Arylporphyrins Containing Exclusively Electron Donating or Withdrawing Groups
DC Field | Value | Language |
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dc.contributor.author | 황광진 | - |
dc.contributor.author | 강민수 | - |
dc.date.accessioned | 2023-06-24T05:40:32Z | - |
dc.date.available | 2023-06-24T05:40:32Z | - |
dc.date.issued | 2023-06 | - |
dc.identifier.issn | 1017-2548 | - |
dc.identifier.issn | 2234-8530 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/31270 | - |
dc.description.abstract | Tetra-aryl substituted A4-type porphyrins (TP, TD, TA) and trans-A2B2 porphyrins (DDP1, AAP1) with electron- donating or withdrawing groups were synthesized. The band gap energy of those porphyrins was calculated from their UV-Vis spectra and CV data. With an electron-withdrawing group, the band gap energy of porphyrin TA increased via the LUMO energy up. Meanwhile, the introduction of an electron-donating group decreased the band gap of porphyrin by HOMO level up as as in the case of porphyrin TD. The band gap (2.19-2.28 eV) of metalloporphyrin PP-Ni was greater than those (1.81-2.06 eV) of non-metalloporphyrins PP due to the LUMO level up. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | 대한화학회 | - |
dc.title | Synthesis and Band Gap Analysis of Meso-Arylporphyrins Containing Exclusively Electron Donating or Withdrawing Groups | - |
dc.title.alternative | Synthesis and Band Gap Analysis of Meso-Arylporphyrins Containing Exclusively Electron Donating or Withdrawing Groups | - |
dc.type | Article | - |
dc.publisher.location | 대한민국 | - |
dc.identifier.doi | 10.5012/jkcs.2023.67.3.175 | - |
dc.identifier.scopusid | 2-s2.0-85166214628 | - |
dc.identifier.wosid | 001026208400002 | - |
dc.identifier.bibliographicCitation | 대한화학회지, v.67, no.3, pp 175 - 180 | - |
dc.citation.title | 대한화학회지 | - |
dc.citation.volume | 67 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 175 | - |
dc.citation.endPage | 180 | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART002967208 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | esci | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordAuthor | Porphyrin | - |
dc.subject.keywordAuthor | Metalloporphyrin | - |
dc.subject.keywordAuthor | Band gap | - |
dc.subject.keywordAuthor | HOMO | - |
dc.subject.keywordAuthor | LUMO | - |
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