Collectively Exhaustive MXene and Graphene Oxide Multilayer for Suppressing Shuttling Effect in Flexible Lithium Sulfur Battery
DC Field | Value | Language |
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dc.contributor.author | Nam, Sanghee | - |
dc.contributor.author | Kim, Jaehwan | - |
dc.contributor.author | Nguyen, Van Hiep | - |
dc.contributor.author | Mahato, Manmatha | - |
dc.contributor.author | Oh, Saewoong | - |
dc.contributor.author | Thangasamy, Pitchai | - |
dc.contributor.author | Ahn, Chi Won | - |
dc.contributor.author | Oh, Il-Kwon | - |
dc.date.accessioned | 2021-11-17T02:40:03Z | - |
dc.date.available | 2021-11-17T02:40:03Z | - |
dc.date.created | 2021-11-17 | - |
dc.date.issued | 2022-05 | - |
dc.identifier.issn | 2365-709X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/20292 | - |
dc.description.abstract | The shuttling effect of lithium polysulfide (LiPS), which leads to the gravest capacity degradation, is one of the critical problems to hindering the commercialization of lithium-sulfur batteries (LSBs). Here, collectively exhaustive Ti3C2Tx MXene and graphene oxide (GO) multilayers are reported to suppress the shuttling effect by utilizing both physical inhibition of micro/mesoporous and chemical absorption of surface functional groups. The abundant surface functional groups of GO and MXene attract the positively charged lithium ion (Li+) and eject the negatively charged polysulfides (S-n(2-)) through electrostatic affinity and repulsion. A simple approach using vacuum filtration is utilized to encapsulate elemental sulfur (S-8) between GO and MXene film (GSM), acting as a permselective separator and functionalized current collector, respectively. The functionally antagonistic GSM directly plays a role in a cathode for LSBs and exhibits a specific capacity of 1425 mAh g(-1) at 0.1C in the initial cycle. The abundant functional groups, which can chemisorb the LiPSs, result in a high cyclic retention of approximate to 85.1% after 500 cycles. Furthermore, a flexible LSB is demonstrated with a PEO-LiTFSI electrolyte based on the flexibility of the exceptionally thin GSM due to the 2D nanomaterials, MXene and graphene oxide. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | WILEY | - |
dc.title | Collectively Exhaustive MXene and Graphene Oxide Multilayer for Suppressing Shuttling Effect in Flexible Lithium Sulfur Battery | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Jaehwan | - |
dc.identifier.doi | 10.1002/admt.202101025 | - |
dc.identifier.wosid | 000710295100001 | - |
dc.identifier.bibliographicCitation | ADVANCED MATERIALS TECHNOLOGIES, v.7, no.5 | - |
dc.relation.isPartOf | ADVANCED MATERIALS TECHNOLOGIES | - |
dc.citation.title | ADVANCED MATERIALS TECHNOLOGIES | - |
dc.citation.volume | 7 | - |
dc.citation.number | 5 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | CATHODES | - |
dc.subject.keywordPlus | MEMBRANE | - |
dc.subject.keywordPlus | HOST | - |
dc.subject.keywordPlus | LIFE | - |
dc.subject.keywordAuthor | multilayer | - |
dc.subject.keywordAuthor | MXene | - |
dc.subject.keywordAuthor | graphene oxide | - |
dc.subject.keywordAuthor | flexible | - |
dc.subject.keywordAuthor | lithium sulfur batteries | - |
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