Effect of liquid recirculation flow on sonochemical oxidation activity in a 28 kHz sonoreactor

Abstract

Sonochemical oxidation activity may be significantly enhanced by optimizing the geometric factors of a sonoreactor and implementing additional physical actions, such as mechanical mixing and gas sparging. This study investigates the effects of liquid recirculation flow on sonochemical oxidation reactions. This was carried out through experimental testing with a 28 kHz bath-type sonoreactor under various liquid heights and flow rates, ranging from 1 lambda to 4.0 lambda and 1.5-6.0 L/min, respectively. The potassium iodide (KI) dosimetry and sonochemiluminescence methods were used in the experiment. With an increase in the liquid height/volume, the pseudo zero-order kinetic constant and the mass of triiodide (I-3(-)) ions fluctuated. The optimal liquid height was 2.0 lambda, 2.5 lambda, and 3.0 lambda, based on the appropriate formation of a cavitation active zone in the reactor. The introduction of a liquid recirculation flow led to a large reduction in sonochemical activity due to the shrinkage of the cavitation active zone. However, the sonochemical activity increased at higher flow rates through the capture of ultrasonic energy at the bottom zone. This increase was attributed to the formation of a strong and expanded active zone limited to the reactor bottom to the height of the recirculation flow. The results demonstrate that applying a high rate liquid flow adjacent to the transducer module may be beneficial for enhanced sonochemical activity.