Ferroelastic to paraelastic phase transition of K3H(SeO4)(2) and Rb3H(SeO4)(2) single crystals studied by nuclear magnetic resonance and external stress
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lim, Ae Ran | - |
dc.contributor.author | Ham, Shin Gyoon | - |
dc.contributor.author | Chang, Jin-Hae | - |
dc.contributor.author | Ichikawa, M. | - |
dc.date.accessioned | 2024-02-27T11:01:34Z | - |
dc.date.available | 2024-02-27T11:01:34Z | - |
dc.date.issued | 2007-02 | - |
dc.identifier.issn | 0370-1972 | - |
dc.identifier.issn | 1521-3951 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/26806 | - |
dc.description.abstract | The temperature dependences of the nuclear magnetic resonance (NMR) and the stress-strain hysteresis curves have been measured for K3H(SeO4)(2) and Rb3H(SeO4)(2) crystals grown using the slow evaporation method. By analysis of the K-39 and Rb-87 NMR results, it has been confirmed that the phase below T-C is ferroelastic with twin domains and that the phase above T-C is paraelastic with a single domain. The ferroelastic domain switching that occurs in the two single crystals due to external stress was also studied. The critical stress values for converting the twin-domain state to the single-domain state were obtained. When external stresses of 0.6 and 0.4 MPa were applied to the K3H(SeO4)(2) and Rb3H(SeO4)(2) crystals, respectively, transitions from twin-domain to single-domain states were observed. The ferroelastic domain switching resulting from an external stress may be associated with the atomic rearrangements of the SeO4 tetrahedra in K3H(SeO4)(2) and Rb3H(SeO4)(2) crystals; the ferroelastic domain switching is explained by the restriction of the rotation of the SeO4 tetrahedra as a result of the breaking of all hydrogen bonds by the external stress. (C) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | - |
dc.format.extent | 8 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Ferroelastic to paraelastic phase transition of K3H(SeO4)(2) and Rb3H(SeO4)(2) single crystals studied by nuclear magnetic resonance and external stress | - |
dc.type | Article | - |
dc.publisher.location | 독일 | - |
dc.identifier.doi | 10.1002/pssb.200541464 | - |
dc.identifier.wosid | 000244209800028 | - |
dc.identifier.bibliographicCitation | PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, v.244, no.2, pp 775 - 782 | - |
dc.citation.title | PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | - |
dc.citation.volume | 244 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 775 | - |
dc.citation.endPage | 782 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | PROTON CONDUCTING PHASE | - |
dc.subject.keywordPlus | IONIC-CONDUCTIVITY | - |
dc.subject.keywordPlus | HYDROGEN-BOND | - |
dc.subject.keywordPlus | CSHSEO4 | - |
dc.subject.keywordPlus | CSHSO4 | - |
dc.subject.keywordPlus | M3H(XO4)(2) | - |
dc.subject.keywordPlus | DEPENDENCE | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | SYMMETRY | - |
dc.subject.keywordPlus | SE | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
350-27, Gumi-daero, Gumi-si, Gyeongsangbuk-do, Republic of Korea (39253)054-478-7170
COPYRIGHT 2020 Kumoh University All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.