Pd-Co bimetallic nanoparticles modified α-FeOOH nanorod for the catalytic reduction of organic pollutants
DC Field | Value | Language |
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dc.contributor.author | Shanmugaraj, Krishnamoorthy | - |
dc.contributor.author | Mangalaraja, Ramalinga Viswanathan | - |
dc.contributor.author | Manikandan, Velu | - |
dc.contributor.author | Campos, Cristian H. | - |
dc.contributor.author | Packiaraj, S. | - |
dc.contributor.author | Aepuru, Radhamanohar | - |
dc.contributor.author | de Leon, J. Noe Diaz | - |
dc.contributor.author | Sathish, Manda | - |
dc.contributor.author | Song, Kwang Soup | - |
dc.date.accessioned | 2024-07-19T02:30:23Z | - |
dc.date.available | 2024-07-19T02:30:23Z | - |
dc.date.issued | 2024-06 | - |
dc.identifier.issn | 2213-2929 | - |
dc.identifier.issn | 2213-3437 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/28799 | - |
dc.description.abstract | The development of most effective reduction catalysts is an essential for promoting the sustainability by minimizing the waste and safeguard the environment. Herein, we prepared palladium-cobalt bimetallic nanoparticles modified on goethite nanorods (PdCo/alpha-FeOOH) as a catalyst for the catalytic degradation of various organic pollutants under mild reaction conditions. The structure and morphology of synthesized catalysts were tested by XRD, FT-IR, BET, SEM, TEM, HR-TEM and XPS techniques. The ultra-small PdCo bimetallic NPs (2.95 +/- 0.5 nm) synthesized onto the surface of alpha-FeOOH nanorod were confirmed by HR-TEM analysis. The prepared catalysts were played an important role in the reduction of toxic nitrocompounds such as (4-nitrophenol (4-NP), 4-nitroaniline (4-NA), 4-(4-nitrophenyl)morpholine (4-NM) and 4-(2-fluoro-4-nitrophenyl)morpholine (4-FNM)) and rhodamine B (RhB) dye. The PdCo/alpha-FeOOH nanocatalyst displayed a greater rate constant (similar to 1.5 min and k(app) = 2.631 min(-1)) compared to their respective mono-metallic counterparts (Pd/alpha-FeOOH and Co/alpha-FeOOH). The reusability results indicated that >97 % of conversion for 4-NP, and RhB dye over 10 consecutive reaction cycles in the batch method. Furthermore, the continuous flow reactor with PdCo/alpha-FeOOH catalyst was constructed, and it showed the ability to eliminate > 99 % of both 4-NP and RhB dye and maintained a degradation rate of >98 % for 20 consecutive recycles. The superior catalytic activity of the PdCo/alpha-FeOOH catalyst compared to other mono-metallic catalysts could be attributed to their particle size and synergistic effect. This study has the potential to facilitate the utilization of the synthesized bimetallic nanostructure in a wider range of other wastewater treatments. | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ELSEVIER SCI LTD | - |
dc.title | Pd-Co bimetallic nanoparticles modified α-FeOOH nanorod for the catalytic reduction of organic pollutants | - |
dc.type | Article | - |
dc.publisher.location | 영국 | - |
dc.identifier.doi | 10.1016/j.jece.2024.112942 | - |
dc.identifier.scopusid | 2-s2.0-85192782281 | - |
dc.identifier.wosid | 001243644400001 | - |
dc.identifier.bibliographicCitation | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v.12, no.3 | - |
dc.citation.title | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING | - |
dc.citation.volume | 12 | - |
dc.citation.number | 3 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | EFFICIENT CATALYST | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE | - |
dc.subject.keywordPlus | DOPED CARBON | - |
dc.subject.keywordPlus | EVOLUTION | - |
dc.subject.keywordPlus | OXIDE | - |
dc.subject.keywordPlus | COMPOSITE | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | GRAPHENE | - |
dc.subject.keywordPlus | PHASE | - |
dc.subject.keywordAuthor | Catalytic reduction | - |
dc.subject.keywordAuthor | Bimetallic nanoparticles | - |
dc.subject.keywordAuthor | 4-Nitrophenol | - |
dc.subject.keywordAuthor | Synergistic effect | - |
dc.subject.keywordAuthor | Continuous flow reactor | - |
dc.subject.keywordAuthor | Rhodamine B | - |
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