Luminescent Cs<sub>8</sub>PbBr<sub>6</sub> <SUP>4+</SUP> Quantum Dots Centered on the Octahedral PbBr<sub>6</sub> <SUP>4-</SUP> Cluster within Zeolite LTA: Exploring the Edge of Three-Dimensional Crystal Structure and Its Stability
DC Field | Value | Language |
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dc.contributor.author | Lim, Hyeon Seung | - |
dc.contributor.author | Jeong, Sang Gil | - |
dc.contributor.author | Park, Gi Beom | - |
dc.contributor.author | Kim, Joon Young | - |
dc.contributor.author | Heo, Nam Ho | - |
dc.contributor.author | Lim, Woo Taik | - |
dc.date.accessioned | 2024-08-08T10:30:19Z | - |
dc.date.available | 2024-08-08T10:30:19Z | - |
dc.date.issued | 2024-07 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.issn | 1520-510X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/28840 | - |
dc.description.abstract | The perovskite quantum dots (QDs) of CsPbX3 (X = Cl, Br, I) exhibit exceptional photoluminescent properties, but their sensitivity to moisture and heat poses a challenge. This study presents a solvent-free synthesis approach for incorporating CsPbBr3 perovskite QDs into zeolite A. The introduction of [Cs8PbBr6](4+) perovskite QDs into the zeolite framework resulted in a highly stable configuration, maintaining its initial luminescence properties even after being underwater or exposed to heat. The structure is determined by 3-dimensional single-crystal crystallography. Each octahedral PbBr64- ion is surrounded by Cs+ ions and [Cs8PbBr6](4+) perovskite QDs being formed at the 32% of the center of a large cavity. Further, [Na12CsBr8](5+) QDs are formed at the very center of another 46% large cavities by combining Cs+, Na+, and Br- ions. The peak in the emission spectrum of Pb,Br,Cs,Na-A is similar to those of the CsPbBr3 nanocrystal, Cs4PbBr6 0-dimensional perovskite QDs, and Pb,Br,H,Cs,Na-FAU(X and Y). This work demonstrates that Pb,Br,Cs,Na-A can be produced using a simplified solvent-free synthesis procedure, which exhibits excellent stability against moisture and heat. Moreover, through a straightforward process, various quantum dots (QDs) can be incorporated into zeolite cavities to develop materials with variety photoluminescent properties. | - |
dc.format.extent | 13 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Luminescent Cs<sub>8</sub>PbBr<sub>6</sub> <SUP>4+</SUP> Quantum Dots Centered on the Octahedral PbBr<sub>6</sub> <SUP>4-</SUP> Cluster within Zeolite LTA: Exploring the Edge of Three-Dimensional Crystal Structure and Its Stability | - |
dc.type | Article | - |
dc.publisher.location | 미국 | - |
dc.identifier.doi | 10.1021/acs.inorgchem.4c01473 | - |
dc.identifier.scopusid | 2-s2.0-85198969515 | - |
dc.identifier.wosid | 001271998500001 | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.63, no.30, pp 13991 - 14003 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 63 | - |
dc.citation.number | 30 | - |
dc.citation.startPage | 13991 | - |
dc.citation.endPage | 14003 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.subject.keywordPlus | NANOCRYSTALS | - |
dc.subject.keywordPlus | CESIUM | - |
dc.subject.keywordPlus | CSPBX3 | - |
dc.subject.keywordPlus | BRIGHT | - |
dc.subject.keywordPlus | BR | - |
dc.subject.keywordPlus | CL | - |
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