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Asymmetric Synthesis of Tetrahydroquinolines via 1,5-Hydride Transfer/Cyclization Catalyzed by Chiral Primary Amine Catalysts

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dc.contributor.authorKang, Young Ku-
dc.contributor.authorKim, Dae Young-
dc.date.accessioned2021-08-12T00:44:16Z-
dc.date.available2021-08-12T00:44:16Z-
dc.date.issued2013-11-11-
dc.identifier.issn1615-4150-
dc.identifier.issn1615-4169-
dc.identifier.urihttps://scholarworks.bwise.kr/sch/handle/2021.sw.sch/13210-
dc.description.abstractChiral primary amine-catalyzed asymmetric CH functionalization has been achieved. In this process, enantiotopic Csp(3)H functionalization at the -position to the nitrogen atom of 4-[ortho-(dialkylamino)phenyl]but-3-en-2-one is activated by chiral 9-amino(9-deoxy)-epi-quinine to afford tetrahydroquinine derivatives with high enantioselectivities (up to 97% ee).-
dc.format.extent6-
dc.language영어-
dc.language.isoENG-
dc.publisherJohn Wiley & Sons Ltd.-
dc.titleAsymmetric Synthesis of Tetrahydroquinolines via 1,5-Hydride Transfer/Cyclization Catalyzed by Chiral Primary Amine Catalysts-
dc.typeArticle-
dc.publisher.location독일-
dc.identifier.doi10.1002/adsc.201300398-
dc.identifier.scopusid2-s2.0-84887843784-
dc.identifier.wosid000328321400004-
dc.identifier.bibliographicCitationAdvanced Synthesis & Catalysis, v.355, no.16, pp 3131 - 3136-
dc.citation.titleAdvanced Synthesis & Catalysis-
dc.citation.volume355-
dc.citation.number16-
dc.citation.startPage3131-
dc.citation.endPage3136-
dc.type.docTypeArticle-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClasssci-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Applied-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusH BOND FUNCTIONALIZATION-
dc.subject.keywordPlusRING-CLOSURE REACTIONS-
dc.subject.keywordPlusHYDRIDE TRANSFER-
dc.subject.keywordPlusC-C-
dc.subject.keywordPlusTRANSFER HYDROGENATION-
dc.subject.keywordPlusSTEREOCHEMICAL ASPECTS-
dc.subject.keywordPlusHETEROCYCLIC SYNTHESIS-
dc.subject.keywordPlusCARBONYL-COMPOUNDS-
dc.subject.keywordPlusALPHA-CYCLIZATION-
dc.subject.keywordPlusTERTIARY-AMINES-
dc.subject.keywordAuthorasymmetric synthesis-
dc.subject.keywordAuthorCH functionalization-
dc.subject.keywordAuthor1-
dc.subject.keywordAuthor5-hydride transfer-
dc.subject.keywordAuthororganocatalysis-
dc.subject.keywordAuthortetrahydroquinolines-
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