Asymmetric Synthesis of Tetrahydroquinolines via 1,5-Hydride Transfer/Cyclization Catalyzed by Chiral Primary Amine Catalysts
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, Young Ku | - |
dc.contributor.author | Kim, Dae Young | - |
dc.date.accessioned | 2021-08-12T00:44:16Z | - |
dc.date.available | 2021-08-12T00:44:16Z | - |
dc.date.issued | 2013-11-11 | - |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.issn | 1615-4169 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/13210 | - |
dc.description.abstract | Chiral primary amine-catalyzed asymmetric CH functionalization has been achieved. In this process, enantiotopic Csp(3)H functionalization at the -position to the nitrogen atom of 4-[ortho-(dialkylamino)phenyl]but-3-en-2-one is activated by chiral 9-amino(9-deoxy)-epi-quinine to afford tetrahydroquinine derivatives with high enantioselectivities (up to 97% ee). | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | Asymmetric Synthesis of Tetrahydroquinolines via 1,5-Hydride Transfer/Cyclization Catalyzed by Chiral Primary Amine Catalysts | - |
dc.type | Article | - |
dc.publisher.location | 독일 | - |
dc.identifier.doi | 10.1002/adsc.201300398 | - |
dc.identifier.scopusid | 2-s2.0-84887843784 | - |
dc.identifier.wosid | 000328321400004 | - |
dc.identifier.bibliographicCitation | Advanced Synthesis & Catalysis, v.355, no.16, pp 3131 - 3136 | - |
dc.citation.title | Advanced Synthesis & Catalysis | - |
dc.citation.volume | 355 | - |
dc.citation.number | 16 | - |
dc.citation.startPage | 3131 | - |
dc.citation.endPage | 3136 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | H BOND FUNCTIONALIZATION | - |
dc.subject.keywordPlus | RING-CLOSURE REACTIONS | - |
dc.subject.keywordPlus | HYDRIDE TRANSFER | - |
dc.subject.keywordPlus | C-C | - |
dc.subject.keywordPlus | TRANSFER HYDROGENATION | - |
dc.subject.keywordPlus | STEREOCHEMICAL ASPECTS | - |
dc.subject.keywordPlus | HETEROCYCLIC SYNTHESIS | - |
dc.subject.keywordPlus | CARBONYL-COMPOUNDS | - |
dc.subject.keywordPlus | ALPHA-CYCLIZATION | - |
dc.subject.keywordPlus | TERTIARY-AMINES | - |
dc.subject.keywordAuthor | asymmetric synthesis | - |
dc.subject.keywordAuthor | CH functionalization | - |
dc.subject.keywordAuthor | 1 | - |
dc.subject.keywordAuthor | 5-hydride transfer | - |
dc.subject.keywordAuthor | organocatalysis | - |
dc.subject.keywordAuthor | tetrahydroquinolines | - |
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