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Enantioselective decarboxylative aldol addition of beta-ketoacids to isatins catalyzed by binaphthyl-modified organocatalyst
- Issue Date
- 10-Jul-2013
- Publisher
- Elsevier BV
- Keywords
- Asymmetric catalysis; Organocatalysis; Aldol addition; 3-Hydroxy oxindole; Isatins; beta-Ketoacids
- Citation
- Tetrahedron Letters, v.54, no.28, pp 3651 - 3654
- Pages
- 4
- Journal Title
- Tetrahedron Letters
- Volume
- 54
- Number
- 28
- Start Page
- 3651
- End Page
- 3654
- ISSN
- 0040-4039
- Abstract
- The catalytic enantioselective decarboxylative aldol addition reaction of isatins with beta-ketoacids promoted by chiral bifunctional organocatalysts have been developed, allowing facile synthesis of the corresponding chiral 3-hydroxy-3-phenacyloxindole derivatives with excellent enantioselectivity (up to 97% ee). (C) 2013 Elsevier Ltd. All rights reserved.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)