Enantio- and diastereoselective Michael addition reactions of alpha-cyanoketones to nitroalkenes catalyzed by binaphthyl-derived organocatalyst
DC Field | Value | Language |
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dc.contributor.author | Lee, Hyun Joo | - |
dc.contributor.author | Woo, Saet Byeol | - |
dc.contributor.author | Kim, Dae Young | - |
dc.date.accessioned | 2021-08-12T03:24:22Z | - |
dc.date.available | 2021-08-12T03:24:22Z | - |
dc.date.issued | 2012-06-27 | - |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/15058 | - |
dc.description.abstract | The catalytic enantioselective and diastereoselective Michael addition reactions promoted by chiral bifunctional organocatalysts are described. The treatment of alpha-cyanoketones with nitroalkenes under mild reaction conditions afforded the corresponding gamma-niro alpha-cyanoketones with excellent diastereoselectivities (up to syn/anti >99/1) and excellent enantioselectivities (up to 99% ee). (C) 2012 Elsevier Ltd. All rights reserved. | - |
dc.format.extent | 4 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | Elsevier BV | - |
dc.title | Enantio- and diastereoselective Michael addition reactions of alpha-cyanoketones to nitroalkenes catalyzed by binaphthyl-derived organocatalyst | - |
dc.type | Article | - |
dc.publisher.location | 영국 | - |
dc.identifier.doi | 10.1016/j.tetlet.2012.04.095 | - |
dc.identifier.scopusid | 2-s2.0-84861532047 | - |
dc.identifier.wosid | 000304851500043 | - |
dc.identifier.bibliographicCitation | Tetrahedron Letters, v.53, no.26, pp 3374 - 3377 | - |
dc.citation.title | Tetrahedron Letters | - |
dc.citation.volume | 53 | - |
dc.citation.number | 26 | - |
dc.citation.startPage | 3374 | - |
dc.citation.endPage | 3377 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | MANNICH-TYPE REACTIONS | - |
dc.subject.keywordPlus | ENANTIOSELECTIVE CONJUGATE ADDITION | - |
dc.subject.keywordPlus | BETA-KETO-ESTERS | - |
dc.subject.keywordPlus | ALPHA,BETA-UNSATURATED KETONES | - |
dc.subject.keywordPlus | QUATERNARY STEREOCENTERS | - |
dc.subject.keywordPlus | 1,3-DICARBONYL COMPOUNDS | - |
dc.subject.keywordPlus | ASYMMETRIC-SYNTHESIS | - |
dc.subject.keywordPlus | HIGHLY EFFICIENT | - |
dc.subject.keywordPlus | CYANO ACETATES | - |
dc.subject.keywordPlus | KETOESTERS | - |
dc.subject.keywordAuthor | Organocatalysis | - |
dc.subject.keywordAuthor | Michael reaction | - |
dc.subject.keywordAuthor | Asymmetric catalysis | - |
dc.subject.keywordAuthor | Cyanoketones | - |
dc.subject.keywordAuthor | Nitroalkenes | - |
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