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Enantio- and diastereoselective Michael addition reactions of alpha-cyanoketones to nitroalkenes catalyzed by binaphthyl-derived organocatalyst

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dc.contributor.authorLee, Hyun Joo-
dc.contributor.authorWoo, Saet Byeol-
dc.contributor.authorKim, Dae Young-
dc.date.accessioned2021-08-12T03:24:22Z-
dc.date.available2021-08-12T03:24:22Z-
dc.date.issued2012-06-27-
dc.identifier.issn0040-4039-
dc.identifier.urihttps://scholarworks.bwise.kr/sch/handle/2021.sw.sch/15058-
dc.description.abstractThe catalytic enantioselective and diastereoselective Michael addition reactions promoted by chiral bifunctional organocatalysts are described. The treatment of alpha-cyanoketones with nitroalkenes under mild reaction conditions afforded the corresponding gamma-niro alpha-cyanoketones with excellent diastereoselectivities (up to syn/anti >99/1) and excellent enantioselectivities (up to 99% ee). (C) 2012 Elsevier Ltd. All rights reserved.-
dc.format.extent4-
dc.language영어-
dc.language.isoENG-
dc.publisherElsevier BV-
dc.titleEnantio- and diastereoselective Michael addition reactions of alpha-cyanoketones to nitroalkenes catalyzed by binaphthyl-derived organocatalyst-
dc.typeArticle-
dc.publisher.location영국-
dc.identifier.doi10.1016/j.tetlet.2012.04.095-
dc.identifier.scopusid2-s2.0-84861532047-
dc.identifier.wosid000304851500043-
dc.identifier.bibliographicCitationTetrahedron Letters, v.53, no.26, pp 3374 - 3377-
dc.citation.titleTetrahedron Letters-
dc.citation.volume53-
dc.citation.number26-
dc.citation.startPage3374-
dc.citation.endPage3377-
dc.type.docTypeArticle-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClasssci-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusMANNICH-TYPE REACTIONS-
dc.subject.keywordPlusENANTIOSELECTIVE CONJUGATE ADDITION-
dc.subject.keywordPlusBETA-KETO-ESTERS-
dc.subject.keywordPlusALPHA,BETA-UNSATURATED KETONES-
dc.subject.keywordPlusQUATERNARY STEREOCENTERS-
dc.subject.keywordPlus1,3-DICARBONYL COMPOUNDS-
dc.subject.keywordPlusASYMMETRIC-SYNTHESIS-
dc.subject.keywordPlusHIGHLY EFFICIENT-
dc.subject.keywordPlusCYANO ACETATES-
dc.subject.keywordPlusKETOESTERS-
dc.subject.keywordAuthorOrganocatalysis-
dc.subject.keywordAuthorMichael reaction-
dc.subject.keywordAuthorAsymmetric catalysis-
dc.subject.keywordAuthorCyanoketones-
dc.subject.keywordAuthorNitroalkenes-
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