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Enantioselective Michael addition of 2-hydroxy-1,4-naphthoquinones to nitroalkenes catalyzed by binaphthyl-derived organocatalysts
- Authors
- Woo, Saet Byeol; Kim, Dae Young
- Issue Date
- 7-May-2012
- Publisher
- Beilstein-Institut
- Keywords
- asymmetric catalysis; Michael addition; 1,4-naphthoquinones; nitroalkenes; organocatalysis
- Citation
- Beilstein Journal of Organic Chemistry, v.8, pp 699 - 704
- Pages
- 6
- Journal Title
- Beilstein Journal of Organic Chemistry
- Volume
- 8
- Start Page
- 699
- End Page
- 704
- ISSN
- 1860-5397
- Abstract
- The highly enantioselective Michael addition of 2-hydroxy-1,4-naphthoquinones to nitroalkenes, promoted by binaphthyl-modified chiral bifunctional organocatalysts is described. This reaction afforded the chiral functionalized naphthoquinones in high yields (81-95%) and excellent enantioselectivities (91-98% ee) under low catalyst loading (1 mol %).
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)