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Catalytic asymmetric Mannich-type reactions of fluorinated ketoesters with N-Boc aldimines in the presence of chiral palladium complexes
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kang, Young Ku | - |
| dc.contributor.author | Kim, Dae Young | - |
| dc.date.accessioned | 2021-08-12T05:44:23Z | - |
| dc.date.available | 2021-08-12T05:44:23Z | - |
| dc.date.issued | 2011-05-04 | - |
| dc.identifier.issn | 0040-4039 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/16540 | - |
| dc.description.abstract | The catalytic enantioselective Mannich reaction promoted by chiral palladium complexes is described. The treatment of alpha-fluoro-beta-ketoesters with N-Boc-aldimines under mild reaction conditions afforded the corresponding beta-aminated alpha-fluoro-beta-ketoesters with excellent enantioselectivities (up to 99% ee). (C) 2011 Elsevier Ltd. All rights reserved. | - |
| dc.format.extent | 3 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | Elsevier BV | - |
| dc.title | Catalytic asymmetric Mannich-type reactions of fluorinated ketoesters with N-Boc aldimines in the presence of chiral palladium complexes | - |
| dc.type | Article | - |
| dc.publisher.location | 영국 | - |
| dc.identifier.doi | 10.1016/j.tetlet.2011.02.087 | - |
| dc.identifier.scopusid | 2-s2.0-79953278559 | - |
| dc.identifier.wosid | 000290075500021 | - |
| dc.identifier.bibliographicCitation | Tetrahedron Letters, v.52, no.18, pp 2356 - 2358 | - |
| dc.citation.title | Tetrahedron Letters | - |
| dc.citation.volume | 52 | - |
| dc.citation.number | 18 | - |
| dc.citation.startPage | 2356 | - |
| dc.citation.endPage | 2358 | - |
| dc.type.docType | Article | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | sci | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.subject.keywordPlus | ENANTIOSELECTIVE CONJUGATE ADDITION | - |
| dc.subject.keywordPlus | ELECTROPHILIC ALPHA-AMINATION | - |
| dc.subject.keywordPlus | BETA-KETO PHOSPHONATES | - |
| dc.subject.keywordPlus | MEDICINAL CHEMISTRY | - |
| dc.subject.keywordPlus | MICHAEL REACTION | - |
| dc.subject.keywordPlus | 1,3-DICARBONYL COMPOUNDS | - |
| dc.subject.keywordPlus | DIELS-ALDER | - |
| dc.subject.keywordPlus | ESTERS | - |
| dc.subject.keywordPlus | CYANOKETONES | - |
| dc.subject.keywordPlus | DERIVATIVES | - |
| dc.subject.keywordAuthor | Mannich reaction | - |
| dc.subject.keywordAuthor | Asymmetric catalysis | - |
| dc.subject.keywordAuthor | Chiral palladium catalysts | - |
| dc.subject.keywordAuthor | alpha-Fluoro-beta-ketoesters | - |
| dc.subject.keywordAuthor | Aldimines | - |
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)