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Asymmetric Mannich-type Reactions of Fluorinated Ketoesters with Binaphthyl-Modified Thiourea Catalysts
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kang, Young Ku | - |
| dc.contributor.author | Yoon, Sung Je | - |
| dc.contributor.author | Kim, Dae Young | - |
| dc.date.accessioned | 2021-08-12T05:45:02Z | - |
| dc.date.available | 2021-08-12T05:45:02Z | - |
| dc.date.issued | 2011-04-20 | - |
| dc.identifier.issn | 0253-2964 | - |
| dc.identifier.issn | 1229-5949 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/16582 | - |
| dc.description.abstract | The catalytic enantioselective Mannich-type reaction promoted by chiral binaphthyl-modified bifunctional organocatalysts is described. The treatment of alpha-fluoro-beta-ketoesters with N-Boc imines under mild reaction conditions afforded the corresponding beta-aminated alpha-fluoro-beta-ketoesters with excellent enantioselectivities (up to 98% ee). | - |
| dc.format.extent | 6 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | 대한화학회 | - |
| dc.title | Asymmetric Mannich-type Reactions of Fluorinated Ketoesters with Binaphthyl-Modified Thiourea Catalysts | - |
| dc.type | Article | - |
| dc.publisher.location | 대한민국 | - |
| dc.identifier.doi | 10.5012/bkcs.2011.32.4.1195 | - |
| dc.identifier.scopusid | 2-s2.0-79954616735 | - |
| dc.identifier.wosid | 000290366200017 | - |
| dc.identifier.bibliographicCitation | Bulletin of the Korean Chemical Society, v.32, no.4, pp 1195 - 1200 | - |
| dc.citation.title | Bulletin of the Korean Chemical Society | - |
| dc.citation.volume | 32 | - |
| dc.citation.number | 4 | - |
| dc.citation.startPage | 1195 | - |
| dc.citation.endPage | 1200 | - |
| dc.type.docType | Article | - |
| dc.identifier.kciid | ART001545192 | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | sci | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.description.journalRegisteredClass | kci | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
| dc.subject.keywordPlus | ENANTIOSELECTIVE CONJUGATE ADDITION | - |
| dc.subject.keywordPlus | ELECTROPHILIC ALPHA-AMINATION | - |
| dc.subject.keywordPlus | BETA-KETO PHOSPHONATES | - |
| dc.subject.keywordPlus | MEDICINAL CHEMISTRY | - |
| dc.subject.keywordPlus | MICHAEL REACTION | - |
| dc.subject.keywordPlus | 1,3-DICARBONYL COMPOUNDS | - |
| dc.subject.keywordPlus | CYANO ACETATES | - |
| dc.subject.keywordPlus | DIELS-ALDER | - |
| dc.subject.keywordPlus | ESTERS | - |
| dc.subject.keywordPlus | CYANOKETONES | - |
| dc.subject.keywordAuthor | Mannich reaction | - |
| dc.subject.keywordAuthor | Asymmetric catalysis | - |
| dc.subject.keywordAuthor | Bifunctional organocatalyst | - |
| dc.subject.keywordAuthor | alpha-Fluoro-beta-ketoesters | - |
| dc.subject.keywordAuthor | N-Boc imines | - |
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)