Voltammetric Studies of Diazocalix[4]crown-6 for Metal Ion Sensing
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Dong, Yunyan | - |
dc.contributor.author | Kim, Tae Hyun | - |
dc.contributor.author | Lee, Chang-Seuk | - |
dc.contributor.author | Kim, Hyun Jung | - |
dc.contributor.author | Lee, Jae Hong | - |
dc.contributor.author | Lee, Joung Hae | - |
dc.contributor.author | Kim, Hasuck | - |
dc.contributor.author | Kim, Jong Seung | - |
dc.date.accessioned | 2021-08-12T06:47:55Z | - |
dc.date.available | 2021-08-12T06:47:55Z | - |
dc.date.issued | 2010-12-20 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.issn | 1229-5949 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/17388 | - |
dc.description.abstract | The complex formation between diazocalix[4]dipropyl (1) and diazocalix[4]crown-6 ether (2) with alkali, alkaline earth and transition metal ions was investigated by voltammetry. Electrochemical properties of compounds 1 and 2 and their selectivity toward metal ions were evaluated in CH3CN solution by comparison of voltammetric behaviors of two phenols in each compound. Compounds 1 and 2 showed almost same voltammetric behavior which is two irreversible oxidation peaks caused by intramolecular hydrogen bonding between two phenols in 1 and 2. While, however, upon interacting with various metal ions, 1 with two propyl ether groups showed no significant changes in voltammetry, 2 with crown ether group caused significant voltammetric changes upon the addition of Ba2+ to 2. Their behavior is closely related to the complex formation by entrapment of metal ion into crown ether cavity, and ion-dipole interaction between metal ion and two phenolic groups in calix[4]crown-6. | - |
dc.format.extent | 4 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | 대한화학회 | - |
dc.title | Voltammetric Studies of Diazocalix[4]crown-6 for Metal Ion Sensing | - |
dc.type | Article | - |
dc.publisher.location | 대한민국 | - |
dc.identifier.doi | 10.5012/bkcs.2010.31.12.3549 | - |
dc.identifier.scopusid | 2-s2.0-78650412151 | - |
dc.identifier.wosid | 000286150900013 | - |
dc.identifier.bibliographicCitation | Bulletin of the Korean Chemical Society, v.31, no.12, pp 3549 - 3552 | - |
dc.citation.title | Bulletin of the Korean Chemical Society | - |
dc.citation.volume | 31 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 3549 | - |
dc.citation.endPage | 3552 | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART001525912 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | CALIXARENES | - |
dc.subject.keywordPlus | CELLS | - |
dc.subject.keywordAuthor | Diazocalixarene | - |
dc.subject.keywordAuthor | Calixcrown | - |
dc.subject.keywordAuthor | Voltammetry | - |
dc.subject.keywordAuthor | Cation recognition | - |
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