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Electrochemical Oxidative Arylsulfonylation and 1,2-Alkyl Shift Sequences of Alkenyl Cyclobutanols for the Synthesis of beta-Sulfonated Cyclopentanones
- Authors
- Kim, Yebin; Kim, Dae Young
- Issue Date
- Mar-2021
- Publisher
- 대한화학회
- Keywords
- Electrochemical oxidation; Sulfonylation; Vinyl cyclobutanols; beta-Sulfonated cyclopentanones; Semipinacol rearrangement
- Citation
- Bulletin of the Korean Chemical Society, v.42, no.3, pp 510 - 513
- Pages
- 4
- Journal Title
- Bulletin of the Korean Chemical Society
- Volume
- 42
- Number
- 3
- Start Page
- 510
- End Page
- 513
- ISSN
- 0253-2964
1229-5949
- Abstract
- A novel process for the synthesis of beta-sulfonated cyclopentanones via electrochemical oxidative radical arylsulfonylation and 1,2-alkyl shift sequences of vinyl cyclobutanols was successfully developed. This approach represents a practical method for the preparation of beta-sulfonated cyclopentanones under environmentally benign reaction conditions.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)