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Synthesis of Trifluoromethylated 4H-1-Benzopyran Derivatives via Photocatalytic Trifluoromethylation/Oxidation/Conjugate Addition, and Cyclization Sequences of Vinyl Phenols

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dc.contributor.authorJang, Jihoon-
dc.contributor.authorKim, Dae Young-
dc.date.accessioned2022-04-28T02:40:22Z-
dc.date.available2022-04-28T02:40:22Z-
dc.date.issued2022-04-
dc.identifier.issn2193-5807-
dc.identifier.issn2193-5815-
dc.identifier.urihttps://scholarworks.bwise.kr/sch/handle/2021.sw.sch/20686-
dc.description.abstractThe objective of this study was to describe a cyclization reaction of photoredox generated ortho-quinone methides using 1,3-diketones for the synthesis of trifluoromethylated 4H-1-benzopyrans with moderate to high yields. This process resulted in in situ formation of trifluoromethylated ortho-quinone methides from 2-vinyl phenols with Umemoto's reagent, followed by conjugate addition and cyclization reaction of 1,3-diketones.-
dc.format.extent4-
dc.language영어-
dc.language.isoENG-
dc.publisherWiley - VCH Verlag GmbH & Co. KG-
dc.titleSynthesis of Trifluoromethylated 4H-1-Benzopyran Derivatives via Photocatalytic Trifluoromethylation/Oxidation/Conjugate Addition, and Cyclization Sequences of Vinyl Phenols-
dc.typeArticle-
dc.publisher.location독일-
dc.identifier.doi10.1002/ajoc.202200052-
dc.identifier.scopusid2-s2.0-85126875772-
dc.identifier.wosid000771870400001-
dc.identifier.bibliographicCitationAsian Journal of Organic Chemistry, v.11, no.4, pp 1 - 4-
dc.citation.titleAsian Journal of Organic Chemistry-
dc.citation.volume11-
dc.citation.number4-
dc.citation.startPage1-
dc.citation.endPage4-
dc.type.docTypeArticle-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusORTHO-QUINONE METHIDES-
dc.subject.keywordPlusFRIEDEL-CRAFTS ALKYLATION-
dc.subject.keywordPlusBETA-KETO ACIDS-
dc.subject.keywordPlusASYMMETRIC-SYNTHESIS-
dc.subject.keywordPlusDECARBOXYLATIVE ALKYLATION-
dc.subject.keywordPlusENANTIOSELECTIVE SYNTHESIS-
dc.subject.keywordPlus4+2 ANNULATION-
dc.subject.keywordPlusFLUORINE-
dc.subject.keywordPlusTETRAHYDROQUINOLINES-
dc.subject.keywordPlusCYCLOPENTANONES-
dc.subject.keywordAuthorortho-Quinone methides-
dc.subject.keywordAuthor4H-benzopyrans-
dc.subject.keywordAuthorphotoredox reaction-
dc.subject.keywordAuthormulticomponent reaction-
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