One-step synthesis of calcium-doped copper oxide nanoparticles as an efficient bifunctional electrocatalyst for sensor and supercapacitor applications
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Vinothkumar, Venkatachalam | - |
dc.contributor.author | Prasad, Gajapaneni Venkata | - |
dc.contributor.author | Chen, Shen-Ming | - |
dc.contributor.author | Sangili, Arumugam | - |
dc.contributor.author | Jang, Seung-Joo | - |
dc.contributor.author | Lim, Hong Chul | - |
dc.contributor.author | Kim, Tae Hyun | - |
dc.date.accessioned | 2023-04-25T02:40:18Z | - |
dc.date.available | 2023-04-25T02:40:18Z | - |
dc.date.issued | 2023-03 | - |
dc.identifier.issn | 2352-152X | - |
dc.identifier.issn | 2352-1538 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/22237 | - |
dc.description.abstract | In this work, a facile and cost-effective coprecipitation method was used to synthesize calcium-doped copper oxide (Ca@CuO) nanoparticles for electrochemical detection of antipsychotic drug perphenazine (PPZ) and symmetric supercapacitor (SSC) applications. Various spectroscopic techniques were employed to analyze the structural and morphological properties of Ca@CuO. The electrochemical behavior of PPZ at Ca@CuO modified screen-printed carbon electrode (SPCE) was investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods. The modified Ca@CuO/SPCE under optimized DPV response showed good linearity to PPZ concentrations in the range of 0.025-996.85 mu M with a low limit of detection (LOD) of 0.0074 mu M. Moreover, the developed sensor demonstrated good selectivity, stability, repeatability, and reproducibility. The real sample analysis of PPZ using the sensor was examined in biological samples with applicable recoveries. More interestingly, the pseudocapacitive type Ca@CuO/NF delivered an excellent specific capacitance of 314.4 F g-1 at 0.2 A g-1 and good stability with 92.7 % retention for 5000 cycles. In addition, the fabricated Ca@CuO// Ca@CuO SSC device displayed an energy density of 11.33 Wh kg- 1 at a power density of 399.8 W kg 1. According to these results, Ca-doped metal oxide can be used as an efficient electrocatalyst for sensor and super capacitor applications. | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | Elsevier BV | - |
dc.title | One-step synthesis of calcium-doped copper oxide nanoparticles as an efficient bifunctional electrocatalyst for sensor and supercapacitor applications | - |
dc.type | Article | - |
dc.publisher.location | 네델란드 | - |
dc.identifier.doi | 10.1016/j.est.2022.106415 | - |
dc.identifier.scopusid | 2-s2.0-85144612766 | - |
dc.identifier.wosid | 000912276000001 | - |
dc.identifier.bibliographicCitation | Journal of Energy Storage, v.59 | - |
dc.citation.title | Journal of Energy Storage | - |
dc.citation.volume | 59 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.subject.keywordPlus | ELECTRODE MATERIAL | - |
dc.subject.keywordPlus | SPECTROPHOTOMETRIC DETERMINATION | - |
dc.subject.keywordPlus | QUANTITATIVE-DETERMINATION | - |
dc.subject.keywordPlus | HIGH-ENERGY | - |
dc.subject.keywordPlus | PERPHENAZINE | - |
dc.subject.keywordPlus | NANOCOMPOSITE | - |
dc.subject.keywordPlus | CUO | - |
dc.subject.keywordPlus | EVOLUTION | - |
dc.subject.keywordPlus | OXYGEN | - |
dc.subject.keywordPlus | CHROMATOGRAPHY | - |
dc.subject.keywordAuthor | Metal-doped metal oxide | - |
dc.subject.keywordAuthor | Antipsychotic drug | - |
dc.subject.keywordAuthor | Human fluids | - |
dc.subject.keywordAuthor | Bifunctional electrocatalyst | - |
dc.subject.keywordAuthor | Symmetric supercapacitor device | - |
dc.subject.keywordAuthor | Electroanalytical method | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(31538) 22, Soonchunhyang-ro, Asan-si, Chungcheongnam-do, Republic of Korea+82-41-530-1114
COPYRIGHT 2021 by SOONCHUNHYANG UNIVERSITY ALL RIGHTS RESERVED.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.