Promoted Overall Water Splitting Catalytic Activity and Durability of Ni<sub>3</sub>Fe Alloy by Designing N-Doped Carbon Encapsulation
DC Field | Value | Language |
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dc.contributor.author | Jeong, Dong In | - |
dc.contributor.author | Lee, Ui Young | - |
dc.contributor.author | Kim, Hyunchul | - |
dc.contributor.author | Bang, Hyeon-Seok | - |
dc.contributor.author | Choi, Hyung Wook | - |
dc.contributor.author | Kim, Jiwon | - |
dc.contributor.author | Choi, Hyuck Gu | - |
dc.contributor.author | Oh, Hyung-Suk | - |
dc.contributor.author | Kang, Bong Kyun | - |
dc.contributor.author | Yoon, Dae Ho | - |
dc.date.accessioned | 2024-06-11T07:03:02Z | - |
dc.date.available | 2024-06-11T07:03:02Z | - |
dc.date.issued | 2024-01 | - |
dc.identifier.issn | 1613-6810 | - |
dc.identifier.issn | 1613-6829 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/26016 | - |
dc.description.abstract | Combining an electrochemically stable material onto the surface of a catalyst can improve the durability of a transition metal catalyst, and enable the catalyst to operate stably at high current density. Herein, the contribution of the N-doped carbon shell (NCS) to the electrochemical properties is evaluated by comparing the characteristics of the Ni3Fe@NCS catalyst with the N-doped carbon shell, and the Ni3Fe catalyst. The synthesized Ni3Fe@NCS catalyst has a distinct overpotential difference from the Ni3Fe catalyst (eta(OER) = 468.8 mV, eta(HER) = 462.2 mV) at (200 and -200) mA cm(-2) in 1 m KOH. In stability test at (10 and -10) mA cm(-2), the Ni3Fe@NCS catalyst showed a stability of (95.47 and 99.6)%, while the Ni3Fe catalyst showed a stability of (72.4 and 95.9)%, respectively. In addition, the in situ X-ray Absorption Near Edge Spectroscopy (XANES) results show that redox reaction appeared in the Ni3Fe catalyst by applying voltages of (1.7 and -0.48) V. The decomposition of nickel and iron due to the redox reaction is detected as a high ppm concentration in the Ni3Fe catalyst through Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) analysis. This work presents the strategy and design of a next-generation electrochemical catalyst to improve the electrocatalytic properties and stability. | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Promoted Overall Water Splitting Catalytic Activity and Durability of Ni<sub>3</sub>Fe Alloy by Designing N-Doped Carbon Encapsulation | - |
dc.type | Article | - |
dc.publisher.location | 독일 | - |
dc.identifier.doi | 10.1002/smll.202307830 | - |
dc.identifier.scopusid | 2-s2.0-85182816397 | - |
dc.identifier.wosid | 001147945000001 | - |
dc.identifier.bibliographicCitation | SMALL | - |
dc.citation.title | SMALL | - |
dc.type.docType | Article; Early Access | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | OXYGEN EVOLUTION | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | NANOSHEETS | - |
dc.subject.keywordAuthor | hydrogen evolution reaction | - |
dc.subject.keywordAuthor | N-doped carbon shell | - |
dc.subject.keywordAuthor | overall water splitting | - |
dc.subject.keywordAuthor | oxygen evolution reaction | - |
dc.subject.keywordAuthor | transition metal alloy | - |
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