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Synthesis of beta-selenylated ketones via iodine-mediated selenylation/1,2-carbon migration sequences of alkenyl alcohols

Authors
Kim, YubinKim, Dae Young
Issue Date
6-Jun-2019
Publisher
Elsevier BV
Keywords
Selenylation; Iodine-mediated reaction; Semipinacol rearrangement; Alkenyl alcohols
Citation
Tetrahedron Letters, v.60, no.23, pp 1538 - 1542
Pages
5
Journal Title
Tetrahedron Letters
Volume
60
Number
23
Start Page
1538
End Page
1542
URI
https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/4471
DOI
10.1016/j.tetlet.2019.05.014
ISSN
0040-4039
Abstract
An iodine-mediated selenylation/1,2-carbon migration sequences of alkenyl alcohols is described. This approach provides a mild and operationally simple access to the synthesis of beta-selenated cyclic ketone derivatives from the coupling reaction of alkenyl alcohols with diselenides. (C) 2019 Elsevier Ltd. All rights reserved.
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