Electrochemical radical arylsulfonylation/semipinacol rearrangement sequences of alkenylcyclobutanols: Synthesis of beta-sulfonated cyclic ketones
DC Field | Value | Language |
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dc.contributor.author | Kim, Yeon Joo | - |
dc.contributor.author | Kim, Dae Young | - |
dc.date.accessioned | 2021-08-11T09:44:02Z | - |
dc.date.available | 2021-08-11T09:44:02Z | - |
dc.date.issued | 2019-05-02 | - |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/4533 | - |
dc.description.abstract | Electrochemical oxidative radical sulfonylation/semipinacol rearrangement sequences of alkenylcyclobutanols have been developed. The reaction proceeds in an undivided electrochemical cell equipped with platinum plate electrodes employing sodium iodide as a redox catalyst and a supporting electrolyte. This approach is environmentally benign by using shelf-stable arylsulfonyl hydrazides as arylsulfonyl radical precursor and electrons as oxidizing reagents. The present protocol offers a facile way to prepare beta-sulfonated cyclic ketone derivatives. (C) 2019 Elsevier Ltd. All rights reserved. | - |
dc.format.extent | 4 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | Elsevier BV | - |
dc.title | Electrochemical radical arylsulfonylation/semipinacol rearrangement sequences of alkenylcyclobutanols: Synthesis of beta-sulfonated cyclic ketones | - |
dc.type | Article | - |
dc.publisher.location | 영국 | - |
dc.identifier.doi | 10.1016/j.tetlet.2019.04.009 | - |
dc.identifier.scopusid | 2-s2.0-85063800485 | - |
dc.identifier.wosid | 000469306100015 | - |
dc.identifier.bibliographicCitation | Tetrahedron Letters, v.60, no.18, pp 1287 - 1290 | - |
dc.citation.title | Tetrahedron Letters | - |
dc.citation.volume | 60 | - |
dc.citation.number | 18 | - |
dc.citation.startPage | 1287 | - |
dc.citation.endPage | 1290 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | VISIBLE-LIGHT PHOTOREDOX | - |
dc.subject.keywordPlus | METAL-FREE SYNTHESIS | - |
dc.subject.keywordPlus | MIGRATION SEQUENCES | - |
dc.subject.keywordPlus | AEROBIC DIFUNCTIONALIZATION | - |
dc.subject.keywordPlus | SEMIPINACOL REARRANGEMENT | - |
dc.subject.keywordPlus | TERMINAL ALKYNES | - |
dc.subject.keywordPlus | CINNAMIC-ACIDS | - |
dc.subject.keywordPlus | SULFUR-DIOXIDE | - |
dc.subject.keywordPlus | RING EXPANSION | - |
dc.subject.keywordPlus | SULFONYLATION | - |
dc.subject.keywordAuthor | Sulfonylation | - |
dc.subject.keywordAuthor | Electrochemical oxidation | - |
dc.subject.keywordAuthor | Semipinacol rearrangement | - |
dc.subject.keywordAuthor | Alkenyl alcohols | - |
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