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Electrochemical trifluoromethylation/semipinacol rearrangement sequences of alkenyl alcohols: synthesis of beta-CF3-substituted ketones
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Jung, Hye Im | - |
| dc.contributor.author | Kim, Yubin | - |
| dc.contributor.author | Kim, Dae Young | - |
| dc.date.accessioned | 2021-08-11T09:44:12Z | - |
| dc.date.available | 2021-08-11T09:44:12Z | - |
| dc.date.issued | 2019-04-07 | - |
| dc.identifier.issn | 1477-0520 | - |
| dc.identifier.issn | 1477-0539 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/4583 | - |
| dc.description.abstract | Electrochemical oxidative radical trifluoromethylation/ semipinacol rearrangement sequences of alkenyl alcohols were developed in this study. This approach is environmentally benign and uses the shelf-stable Langlois reagent as a trifluoromethyl radical precursor and electrons as the oxidizing reagents. The present protocol offers a facile route to prepare beta-trifluoromethylated ketone derivatives. | - |
| dc.format.extent | 5 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | Royal Society of Chemistry | - |
| dc.title | Electrochemical trifluoromethylation/semipinacol rearrangement sequences of alkenyl alcohols: synthesis of beta-CF3-substituted ketones | - |
| dc.type | Article | - |
| dc.publisher.location | 영국 | - |
| dc.identifier.doi | 10.1039/c9ob00373h | - |
| dc.identifier.scopusid | 2-s2.0-85063501108 | - |
| dc.identifier.wosid | 000462795100003 | - |
| dc.identifier.bibliographicCitation | Organic and Biomolecular Chemistry, v.17, no.13, pp 3319 - 3323 | - |
| dc.citation.title | Organic and Biomolecular Chemistry | - |
| dc.citation.volume | 17 | - |
| dc.citation.number | 13 | - |
| dc.citation.startPage | 3319 | - |
| dc.citation.endPage | 3323 | - |
| dc.type.docType | Article | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | sci | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.subject.keywordPlus | VISIBLE-LIGHT PHOTOREDOX | - |
| dc.subject.keywordPlus | C-H TRIFLUOROMETHYLATION | - |
| dc.subject.keywordPlus | SEMIPINACOL REARRANGEMENT | - |
| dc.subject.keywordPlus | ASYMMETRIC-SYNTHESIS | - |
| dc.subject.keywordPlus | MIGRATION SEQUENCES | - |
| dc.subject.keywordPlus | RING EXPANSION | - |
| dc.subject.keywordPlus | FLUORINE | - |
| dc.subject.keywordPlus | DIFUNCTIONALIZATION | - |
| dc.subject.keywordPlus | CONSTRUCTION | - |
| dc.subject.keywordPlus | FUNCTIONALIZATION | - |
| dc.subject.keywordAuthor | Electrochemistry | - |
| dc.subject.keywordAuthor | trifluoromethylation | - |
| dc.subject.keywordAuthor | semipinacol rearrangement | - |
| dc.subject.keywordAuthor | alkenyl alcohols | - |
| dc.subject.keywordAuthor | β-CF3-substituted ketones | - |
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)