Electrochemical Radical Selenylation/1,2-Carbon Migration and Dowd Beckwith-Type Ring-Expansion Sequences of Alkenylcyclobutanols
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Yeon Joo | - |
dc.contributor.author | Kim, Dae Young | - |
dc.date.accessioned | 2021-08-11T10:23:41Z | - |
dc.date.available | 2021-08-11T10:23:41Z | - |
dc.date.issued | 2019-02-15 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.issn | 1523-7052 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/4722 | - |
dc.description.abstract | Electrochemical oxidative radical selenylation/ 1,2 -carbon migration and Dowd-Beckwith-type ring-expansion sequences of alkenylcyclobutanols were developed in this study. This approach is environmentally benign and uses shelf-stable diselenides as selenium radical precursors and electrons as oxidizing reagents. The present protocol offers a facile way to prepare beta-selenated cyclic ketone derivatives. Under Dowd-Beckwith-type rearrangement, it can afford the corresponding one-carbon ring-expanded ketones. | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | American Chemical Society | - |
dc.title | Electrochemical Radical Selenylation/1,2-Carbon Migration and Dowd Beckwith-Type Ring-Expansion Sequences of Alkenylcyclobutanols | - |
dc.type | Article | - |
dc.publisher.location | 미국 | - |
dc.identifier.doi | 10.1021/acs.orglett.8b04041 | - |
dc.identifier.scopusid | 2-s2.0-85061243973 | - |
dc.identifier.wosid | 000459366800037 | - |
dc.identifier.bibliographicCitation | Organic Letters, v.21, no.4, pp 1021 - 1025 | - |
dc.citation.title | Organic Letters | - |
dc.citation.volume | 21 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 1021 | - |
dc.citation.endPage | 1025 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | VISIBLE-LIGHT PHOTOREDOX | - |
dc.subject.keywordPlus | ASYMMETRIC-SYNTHESIS | - |
dc.subject.keywordPlus | H FUNCTIONALIZATION | - |
dc.subject.keywordPlus | ARYLBORONIC ACIDS | - |
dc.subject.keywordPlus | ARYL MIGRATION | - |
dc.subject.keywordPlus | BOND FORMATION | - |
dc.subject.keywordPlus | C-SE | - |
dc.subject.keywordPlus | REARRANGEMENT | - |
dc.subject.keywordPlus | SOLVENT | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordAuthor | Electrochemistry | - |
dc.subject.keywordAuthor | Radical Selenylation/1 | - |
dc.subject.keywordAuthor | 2-Carbon Migration | - |
dc.subject.keywordAuthor | Dowd−Beckwith-Type Ring-Expansion | - |
dc.subject.keywordAuthor | Alkenylcyclobutanols | - |
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