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A Novel Superconcentrated Aqueous Electrolyte to Improve the Electrochemical Performance of Calcium-ion Batteries

Authors
Lee, ChangHeeJeong, Soon-Ki
Issue Date
Dec-2016
Publisher
Chemical Society of Japan/Nippon Kagakukai
Keywords
Calcium-ion battery; Superconcentrated aqueous electrolyte; CuHCF electrode
Citation
Chemistry Letters, v.45, no.12, pp 1447 - 1449
Pages
3
Journal Title
Chemistry Letters
Volume
45
Number
12
Start Page
1447
End Page
1449
URI
https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/8576
DOI
10.1246/cl.160769
ISSN
0366-7022
1348-0715
Abstract
Herein, we applied a novel superconcentrated aqueous electrolyte in calcium-ion batteries for the first time to improve electrochemical performance by decreasing the hydration number and radius of calcium ions. Their charge/discharge capacities with the superconcentrated electrolyte were ca. 13% higher than that with the dilute electrolyte. The cycling performance improved quite remarkably in the superconcentrated electrolyte, because of the suppression of structural collapse of copper hexacyanoferrate used as the electrode. The results have been confirmed through X-ray diffraction results.
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