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Visible light photoredox-catalyzed alkylation/ring expansion sequences of 1-(1-arylvinyl)cyclobutanol derivatives
- Authors
- Kwon, Su Jin; Kim, Yeon Joo; Kim, Dae Young
- Issue Date
- 28-Sep-2016
- Publisher
- Elsevier BV
- Keywords
- Bromomalonates; Photocatalysis; Radical reaction; 1,2-Carbon migration
- Citation
- Tetrahedron Letters, v.57, no.39, pp 4371 - 4374
- Pages
- 4
- Journal Title
- Tetrahedron Letters
- Volume
- 57
- Number
- 39
- Start Page
- 4371
- End Page
- 4374
- ISSN
- 0040-4039
- Abstract
- A visible light-mediated photocatalytic bis(alkoxycarbonypmethylationtring expansion of alkenyl cyclobutanols is described. This approach provides a mild and operationally simple access to the synthesis of bis(alkoxycarbonyl)methyl-substituted cyclic ketones from the coupling reaction of 1-(1-arylvinyl)cyclobutanols with aryl bromomalonates. (C) 2016 Elsevier Ltd. All rights reserved.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)