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Viscosity Blending Approach for 22.42% Efficient Perovskite Solar Cells

Authors
Shin, G.S.[Shin, G.S.]Kim, J.-H.[Kim, J.-H.]Lee, S.-U.[Lee, S.-U.]Park, N.-G.[Park, N.-G.]
Issue Date
Aug-2021
Publisher
John Wiley and Sons Inc
Keywords
2-Methoxyethanol; Dimethylacetamide; Dimethylformamide; Perovskite solar cell; Viscosity blending
Citation
Bulletin of the Korean Chemical Society, v.42, no.8, pp.1112 - 1120
Indexed
SCIE
SCOPUS
KCI
Journal Title
Bulletin of the Korean Chemical Society
Volume
42
Number
8
Start Page
1112
End Page
1120
URI
https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/91767
DOI
10.1002/bkcs.12331
ISSN
0253-2964
Abstract
We report here the viscosity blending approach toward high efficiency perovskite solar cells. A binary solvent is introduced in the precursor solution, where 2-methoxyethaol (2ME) is mixed with dimethylformamide (DMF) or dimethylacetamide (DMAc). Viscosity of the binary solvent system is estimated by calculating the viscosity blending number. For the ratio of DMF (DMAc): 2ME = 75:25 leading to the viscosity of 1.0317 (1.1699) cSt, a forward-scanned power conversion efficiency (PCE) of 22.42% is achieved along with photocurrent density of 25.46 mA/cm2, voltage of 1.122 V and fill factor of 0.785, which is higher than the PCE of 20.59% for the single DMF solvent. The binary solvent with optimal viscosity is found to be beneficial to reducing trap density and improving carrier lifetime even in thicker perovskite film. © 2021 Korean Chemical Society, Seoul & Wiley-VCH GmbH
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