Polysilane계 전구체 고분자를 사용한 리튬 이온 전지 음극재용 무기물의 제조Polysilane-Based Ceramics as Anodes in Lithium Ion Batteries
- Other Titles
- Polysilane-Based Ceramics as Anodes in Lithium Ion Batteries
- Authors
- 허태환; 임희은; 김용석; 주용락; 곽영제
- Issue Date
- Apr-2014
- Publisher
- 한국섬유공학회
- Keywords
- lithium ion battery; polysilane; discharge capacity; pre-ceramic polymer
- Citation
- 한국섬유공학회지, v.51, no.2, pp.101 - 106
- Journal Title
- 한국섬유공학회지
- Volume
- 51
- Number
- 2
- Start Page
- 101
- End Page
- 106
- URI
- http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/10473
- ISSN
- 1225-1089
- Abstract
- Two different polysilanes, poly(methyl(phenyl)silane) (PMPS) and poly(methyl(phenyl)silane-co-methyl (vinyl)silane) (PMPS-co-PMVS), were synthesized as precursor polymers to ceramics as anodes in lithium ion batteries. Upon pyrolysis at 1000 oC, the polysilanes yielded ceramics with a Si content of 67−70%. The vinyl group containing PMPS-co-PMVS showed a higher ceramic yield than that containing PMPS due to the thermal crosslinking reactions between the vinyl groups. The ceramic products were characterized using elemental analysis, Fourier transform-infrared spectroscopy, thermogravimetry, X-ray diffractometry, and atomic force microscopy. It was revealed that the ceramics from PMPS-co-PMVS had a higher Si atomic content, had more Si-Si bonds, and a more crystalline structure than those from PMPS. The discharge capacities of the ceramics were less than 200 mAh/g, but they showed excellent cycling performance, maintaining their capacities after 100 charge/discharge cycles.
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