Sr3Bi2(SeO3)(6)center dot H2O: A novel anionic layer consisting of second-order Jahn-Teller (SOJT) distortive cations
DC Field | Value | Language |
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dc.contributor.author | Ahn, Hyun Sun | - |
dc.contributor.author | Lee, Eun Pyo | - |
dc.contributor.author | Chang, Hong-Young | - |
dc.contributor.author | Lee, Dong Woo | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-03-08T18:00:50Z | - |
dc.date.issued | 2015-01 | - |
dc.identifier.issn | 0022-4596 | - |
dc.identifier.issn | 1095-726X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/10006 | - |
dc.description.abstract | A new layered bismuth selenite hydrate material, Sr3Bi2(SeO3)(6)center dot H2O has been synthesized through a hydrothermal reaction using SrCO3, Bi2O3, SeO2, and water as reagents. The crystal structure of the reported material has been determined by single crystal X-ray diffraction analysis. The anionic layered framework of Sr3Bi2(SeO3)6 center dot H2O consists of polyhedra of second-order Jahn-Teller (SOJT) distortive cations, Bi3+ and Se4+. Attributable to the variable and asymmetric coordination geometry of the constituent cations, a rich structural chemistry including uni-dimensional bands and linkers is observed in the layer. The material is thermally stable up to about 390 degrees C and starts decomposing due to the sublimation of SeO2 above the temperature. The UV-vis diffuse reflectance spectrum suggests a band gap of 3.3 eV. Elemental analysis, infrared spectrum, local dipole moment calculations, and electronic structure calculations are also reported. (C) 2014 Elsevier Inc. All rights reserved. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE | - |
dc.title | Sr3Bi2(SeO3)(6)center dot H2O: A novel anionic layer consisting of second-order Jahn-Teller (SOJT) distortive cations | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.jssc.2014.09.018 | - |
dc.identifier.bibliographicCitation | JOURNAL OF SOLID STATE CHEMISTRY, v.221, pp 73 - 78 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000347263700010 | - |
dc.identifier.scopusid | 2-s2.0-84908200567 | - |
dc.citation.endPage | 78 | - |
dc.citation.startPage | 73 | - |
dc.citation.title | JOURNAL OF SOLID STATE CHEMISTRY | - |
dc.citation.volume | 221 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordAuthor | Hydrothermal synthesis | - |
dc.subject.keywordAuthor | Crystal structure | - |
dc.subject.keywordAuthor | Selenite | - |
dc.subject.keywordAuthor | Second-order Jahn-Teller (SOJT) distortion | - |
dc.subject.keywordAuthor | X-ray diffraction | - |
dc.subject.keywordPlus | NEUTRON POWDER DIFFRACTION | - |
dc.subject.keywordPlus | BOND-VALENCE PARAMETERS | - |
dc.subject.keywordPlus | MIXED-METAL SELENITES | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | MAGNETIC-PROPERTIES | - |
dc.subject.keywordPlus | ELECTRON LOCALIZATION | - |
dc.subject.keywordPlus | FRAMEWORK STRUCTURES | - |
dc.subject.keywordPlus | LONE PAIRS | - |
dc.subject.keywordPlus | OXIDES | - |
dc.subject.keywordPlus | BR | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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