Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)(2), KIn(TeO3)(2), RbInTe3O8, and CsInTe3O8
DC Field | Value | Language |
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dc.contributor.author | Bae, Su-whan | - |
dc.contributor.author | Kim, Choong-Yeol | - |
dc.contributor.author | Lee, Dong Woo | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-03-08T20:58:48Z | - |
dc.date.issued | 2014-10 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.issn | 1520-510X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/11708 | - |
dc.description.abstract | Four new alkali metal indium tellurites, NaIn(TeO3)(2), KIn(TeO3)(2), RbInTe3O8, and CsInTe3O8, have been prepared through hydrothermal and solid state synthesis reactions using corresponding alkali metal carbonates, In2O3 [or In(NO3)(3)center dot xH(2)O], and TeO2. The structures of the reported materials have been determined by powder and single crystal X-ray diffraction. The mixed indium tellurites reveal a rich structural chemistry with different channel structures. NaIn(TeO3)(2) shows 8-membered rings, whereas stoichiometrically similar KIn(TeO3)(2) exhibits both 8- and 12-membered rings in the frameworks. Isostructural RbInTe3O8 and CsInTe3O8 reveal three-dimensional frameworks consisting of InO6, TeO3, and TeO4 groups. Close structural examination suggests that the alkali metal cation size and variable coordination modes of Te4+ cations cooperatively influence the framework geometries of the new mixed metal tellurites. Detailed characterizations including spectroscopic, elemental, and thermal analyses are introduced. Local dipole moments and out-of-center distortions for the constituent polyhedra are also reported. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)(2), KIn(TeO3)(2), RbInTe3O8, and CsInTe3O8 | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ic502108a | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.53, no.20, pp 11328 - 11334 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000343527700065 | - |
dc.identifier.scopusid | 2-s2.0-84908254343 | - |
dc.citation.endPage | 11334 | - |
dc.citation.number | 20 | - |
dc.citation.startPage | 11328 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 53 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordPlus | BOND-VALENCE PARAMETERS | - |
dc.subject.keywordPlus | LONE-PAIR CATION | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | NONCENTROSYMMETRIC TELLURITE | - |
dc.subject.keywordPlus | 2ND-HARMONIC GENERATION | - |
dc.subject.keywordPlus | DISTORTION | - |
dc.subject.keywordPlus | GLASSES | - |
dc.subject.keywordPlus | ANION | - |
dc.subject.keywordPlus | IV | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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